RESUMEN:Se obtuvieron recubrimientos poliméricos de policaprolactona-quitosano, aplicados mediante la técnica Dip-Coating, sobre sustratos de Ti6Al4V tratados químicamente con NaOH. Con base en los análisis SEM y los espectros infrarrojos, se observó que la cantidad de policaprolactona en el recubrimiento presentó un efecto en la retención de quitosano en la superficie, relacionado con la emisión del enlace R-OH y las características morfológicas. Los espectros de impedancia realizados a las películas poliméricas, mostraron procesos relacionados con fenómenos de adsorción de especies iónicas hasta la formación de monocapas en la superficie. Igualmente, estos espectros mostraron fenómenos de transferencia de carga generados por las características morfológicas de los recubrimientos, como sus porosidades, densidad y homogeneidad. La inmersión de los sustratos recubiertos en una solución SBF durante 8 días, permitió observar su capacidad de adsorción de calcio mediante la nucleación y precipitación de fosfatos de calcio, mostrando un carácter bioactivo frente al medio. ABSTRACT: Obtention, characterization and in vitro evaluation of polycaprolactone-chitosan coatings growth on chemically treated Ti6Al4V alloy. Polymeric coatings were obtained polycaprolactone-chitosan. The coatings were applied by dip-coating technique, on Ti6Al4V substrates chemically treated with NaOH solution. Based on SEM morphological analysis and infrared spectra, it was observed that the amount of polycaprolactone in the coating obtained had an effect in retaining the chitosan on the surface, associated with the emission of R-OH bond and the morphological characteristics. Impedance spectra performed on the polymeric films showed phenomena related processes adsorption of ionic species to monolayer formation on the surface. These spectra showed equally charge transfer phenomena generated by the morphological characteristics of the coatings, such as its porosity, density and homogeneity. The coated substrate was immersing in SBF solution for 8 days, allowed to observe its adsorption capacity of calcium through nucleation and precipitation of calcium phosphates, bioactive character displaying a front medium.
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