The hierarchically structured Fe3O4-MnO2-ZIF-8 composite was successfully synthesized and applied
to activate peroxymonosulfate (PMS) for the degradation of bisphenol
A (BPA) and other organic pollutants for the first time. Catalytic
experiments revealed that the as-prepared Fe3O4-MnO2-ZIF-8 showed highly efficient catalytic activity
and deep mineralization for BPA because of the loading of ZIF-8. When
60 mg/L BPA was degraded by the Fe3O4-MnO2-ZIF-8/PMS system, the removal efficiency of BPA reached 100%
within 15 min and the TOC removal efficiency reached 80% within 9
min, values that were much higher than those of the catalysts reported
recently. Fe3O4-MnO2-ZIF-8 can be
separated conveniently from the aqueous phase under magnetic field
control and shows better recyclability. Simultaneously, the Fe3O4-MnO2-ZIF-8/PMS system shows an excellent
removal capability for other organic pollutants, such as phenol, tetracycline, p-hydroxybenzoic acid, and rhodamine B. Through radical
quenching experiments and electron paramagnetic resonance tests, the
mechanism of activation of PMS by Fe3O4-MnO2-ZIF-8 was investigated. ZIF-8 loaded on the surface of the
Fe3O4-MnO2 composite can accept electrons
generated from the Mn(II)/Mn(III)/Mn(IV) redox conjugate triplet and
react with PMS to generate more •OH and SO4
•–, thus significantly enhancing the catalytic
performance. Additionally, on the basis of GC-MS analysis, the intermediates
in the process of BPA degradation were tested and the possible degradation
pathway was determined. This study indicates that Fe3O4-MnO2-ZIF-8 is a highly efficient catalytic material
for PMS-based AOPs for the removal of various pollutants from water.
Frequently occurring oil spill accidents have caused
tremendous
pollution of the ecological environment. Although various oil–water
separation strategies have been developed, the design of efficient
oil–water separation materials still remains a significant
challenge. In this study, we report a controllable and scalable method
for the fabrication of wettability-switchable membranes (MCPP) that
achieved a smart temperature response and efficient emulsion separation.
The pore structure of the membrane was precisely controlled by the
amount of natural microfibril cellulose and MnO2 nanowires.
The tensile strength of the membrane was significantly increased to
2.4 MPa with the introduction of poly(vinylidene difluoride). The
temperature sensitivity of poly(N-isopropylacrylamide)
resulted in a reversible wettability switch of the MCPP membrane,
achieving temperature-controlled smart separation for emulsions. Interestingly,
the excellent photothermal conversion properties of MnO2 nanowires realized the switch of membrane surface wettability and
oil viscosity reduction, further increasing the emulsion separation
performance. The MCPP membrane shows high separation permeance (O/W,
4300–5000 L m–2 h–1 bar–1; W/O, 5000–17000 L m–2 h–1 bar–1) and separation efficiency
(>99.4%) for a variety of emulsions. The scalable preparation,
smart
temperature-sensitive wettability switch, excellent emulsion separation
performance, and good reusability provide the basis for the practical
application of this membrane in water purification fields.
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