Bi(3+)/Ln(3+):YVO(4) nanocrystals with a mean size of 6 nm are prepared through a mixed solvothermal route. With Bi(3+) doping, the excitation band corresponding to the Ln(3+) emission is shifted from 280 nm to 345 nm, owing to the occurrence of Bi(3+) --> V(5+) metal-metal charge transfer and the subsequent energy transfer to Ln(3+) ions. Under near-ultraviolet excitation, the emission color of Bi(3+)/Ln(3+):YVO(4) nanophosphors can be easily tuned by changing the Ln(3+) ions.

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