Because of their large theoretical capacity and relatively high electronic conductivity, transition metal selenides have been investigated as potential anodes for energy storage applications. On the other hand, the quick...
In comparison to lithium-ion batteries, sodium-ion batteries (SIBs) have been proposed as an alternative for large-scale energy storage. However, finding an anode material that can overcome the sluggish electrochemical reaction...
An interfacial covalent bonding strategy is proposed to synthesis of MXene-stabilized Sb2Se3 nanotube hybrid. As anode, the prepared Sb2Se3@NC/MXene exhibits enhanced sodium-ion batteries performance in half/full batteries in terms of...
Due to its properties (stable, affordable and non‐toxic), titanium dioxide (TiO2) has a promising future as electrode material for sodium‐ion batteries (SIBs). Its Na+ insertion/deinsertion mechanism, on the other hand, results in poor electronic conductivity and sluggish ionic diffusivity, leading to rapid capacity fading. Herein, a molten salt method is employed to creat abundant carbon pores framework, being capable of supporting plentiful ultra‐fine TiO2 adhering (U‐TiO2/C). With this unique porous structure of lots of exposed active sites, the U‐TiO2/C composite provides a faster ions transport and volume expansion buffer zone during cycling. As anode for SIBs, the U‐TiO2/C manifests splendid electrochemical performance. Specifically, the U‐TiO2/C electrode delivers a high capacity of 202.7 mAh g−1 after 100 cycles at 0.1 A g−1 and 91.4 mAh g−1 at 1.0 A g−1 after 160 cycles. Even with the increased current density to 10.0 A g−1, the U‐TiO2/C electrode still performs a high capacity of 69.5 mAh g−1 after 2500 cycles. Detailed kinetic analysis has been investigated to quantificationally demonstrate that the surface pseudocapacitive storage behavior plays a dominant role in the enhanced sodium storage.
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