Pose estimation is a particularly important link in the task of robotic bin-picking. Its purpose is to obtain the 6D pose (3D position and 3D posture) of the target object. In real bin-picking scenarios, noise, overlap, and occlusion affect accuracy of pose estimation and lead to failure in robot grasping. In this paper, a new point-pair feature (PPF) descriptor is proposed, in which curvature information of point-pairs is introduced to strengthen feature description, and improves the point cloud matching rate. The proposed method also introduces an effective point cloud preprocessing, which extracts candidate targets in complex scenarios, and, thus, improves the overall computational efficiency. By combining with the curvature distribution, a weighted voting scheme is presented to further improve the accuracy of pose estimation. The experimental results performed on public data set and real scenarios show that the accuracy of the proposed method is much higher than that of the existing PPF method, and it is more efficient than the PPF method. The proposed method can be used for robotic bin-picking in real industrial scenarios.