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The characteristic scale of flow in micro–nanochannels is generally in the range of 0.01  μm∼1  μm. When crude oil passes through micro-nano channels and tight reservoirs, it shows obvious nonlinear seepage characteristics, which does not conform to the continuity assumption of fluid. Therefore, a non-Newtonian model of crude oil flowing in micro-nano channels and tight reservoirs under the action of shear stress is established, and the relationship between flow rate and apparent viscosity and shear rate is analyzed. The experiment of crude oil flow in micro-nano channels and tight oil reservoir cores shows that the model can be used to describe the nonlinear seepage law of liquid through the nonlinear fitting. The power law index of the oil-phase power-law non-Newtonian fluid is greater than 1 at the micro-nano scale, which conforms to the flow characteristics of the expansive fluid, thus verifying the effectiveness of the non-Newtonian model. In addition, the study of apparent viscosity and shear rate of non-Newtonian fluid shows that the increasing and decreasing trends of flow rate and shear rate and the changing trends of flow rate and pressure gradient are consistent, and shear rate can be used to describe the characteristics of fluid instead of the pressure gradient.

Porous carbon nanofibers doped with nickel (Ni) were successfully fabricated through electrospinning, carbonization, and CO2 activation techniques using polyacrylonitrile (PAN) and petroleum pitch as carbon sources and nickel acetate as the dopant. During the activation process, Ni was reduced and dispersed in situ on the carbon matrix. The effects of Ni doping content on the morphology and structure of the carbon nanofibers were systematically investigated using SEM, TEM, XPS, XRD, Raman, and BET analyses. The experimental results revealed that the prepared materials had a hierarchically porous structure and that Ni nanoparticles played multiple roles in the preparation process, including catalyzing pore expansion and catalytic graphitization. However, particle agglomeration and fiber fracture occurred when the Ni content was high. In the adsorption/desorption experiments, the sample with 10 wt% Ni doping exhibited the highest specific surface area and micropore volume of 750.7 m2/g and 0.258 cm3/g, respectively, and had the maximum hydrogen storage capacity of 1.39 wt% at 298 K and 10 MPa. The analyses suggested that the hydrogen adsorption mechanism contributed to enhanced H2 adsorption by the spillover effect in addition to physisorption.

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