Water-based renewable energy cycle involved in water splitting, fuel cells, and metal-air batteries has been gaining increasing attention for sustainable generation and storage of energy. The major challenges in these technologies arise due to the poor kinetics of the oxygen reduction reaction (ORR) and the oxygen evolution reactions (OER), besides the high cost of the catalysts. Attempts to address these issues have led to the development of many novel and inexpensive catalysts as well as newer mechanistic insights, particularly so in the last three-four years when more catalysts have been investigated than ever before. With the growing emphasis on bifunctionality, that is, materials that can facilitate both reduction and evolution of oxygen, this review is intended to discuss all major families of ORR, OER, and bifunctional catalysts such as metals, alloys, oxides, other chalcogenides, pnictides, and metal-free materials developed during this period in a single platform, while also directing the readers to specific and detailed review articles dealing with each family. In addition, each section highlights the latest theoretical and experimental insights that may further improve ORR/OER performances. The bifunctional catalysts being sufficiently new, no consensus appears to have emerged about the efficiencies. Therefore, a statistical analysis of their performances by considering nearly all literature reports that have appeared in this period is presented. The current challenges in rational design of these catalysts as well as probable strategies to improve their performances are presented.

Even though the anion exchange membrane fuel cells have many advantages, the stability of their electrocatalysts for oxygen reduction reaction (ORR) has remained remarkably poor. We report here on the ultrathin twisty PdNi-alloy nanowires (NWs) exhibiting a very low reaction overpotential with an E 1/2 ∼ 0.95 V versus RHE in alkaline media maintained over 200 K cycles, the highest ever recorded for an electrocatalyst. The mass activity of the used NWs is >10 times higher than fresh commercial Pt/C. Therein, Ni improves the Pd d-band center for a more efficient ORR, and its leaching continuously regenerates the surface active sites. The twisty nanowire morphology imparts multiple anchor points on the electrode surface to arrest their detachment or coalescence and extra stability from self-entanglement. The significance of the NW morphology was further confirmed from the high-temperature durability studies. The study demonstrates that tailoring the number of contact points to the electrode-surface may help realize commercial-grade stability in the highly active electrocatalysts.

Selective oxidation of amines to imines using sunlight as clean and renewable energy source is an important but challenging chemical transformation because of high reactivity of the generated imines and lack of visible light-responsive materials with high conversion rates. In addition, oxygen gas has to be purged in the reaction mixture in order to increase the reaction efficiency which, in itself, is an energy-consuming process. Herein, we report, for the first time, the use of Ag 3 PO 4 as an excellent photocatalyst for the oxidative coupling of benzyl amines induced by ambient air in the absence of any external source of molecular oxygen at room temperature. The conversion efficiency for the selective oxidation of benzyl amine was found to be greater than 95% with a selectivity of >99% after 40 min of light irradiation indicating an exceptionally high conversion efficiency with a rate constant of 0.002 min −1 , a turnover frequency of 57 h −1 , and a quantum yield of 19%, considering all of the absorbed photons. Ag 3 PO 4 , however, is known for its poor photostability owing to a positive conduction band position and a favorable reduction potential to metallic silver. Therefore, we further employed a simple catalyst regeneration strategy and showed that the catalyst can be recycled with negligible loss of activity and selectivity.

No abstract

Carbon quantum dots obtained from polyethylene exhibit large oxygen enrichment properties in solution enabling catalytic photo-oxidation reactions without artificial oxygen enrichment.