An inverse relationship has been documented by previous studies between antecedent Eurasian winter snow cover (EWSC) and all-India summer monsoon rainfall. Because both China and India are strongly influenced by the Asian monsoon system, it may be reasonable to ask whether a similar relationship exists between the EWSC and summer rainfall over China. This study seeks an answer to this question.Only a weak interannual relationship is found between the EWSC and summer rainfall over China as a whole. This weak EWSC-rainfall linkage occurs only when the averaged rainfall over the entire country is used. By dividing the country into several geographical regions based on observed features in the interannual variability of rainfall, we find much stronger regional rainfall-EWSC relationships. A strong in-phase EWSC-rainfall relationship is found in southern and northern China, whereas an inverse EWSC-rainfall relationship appears in the western, central, and north-eastern parts of China. Thus, EWSC may be a useful predictor for regional Chinese summer rainfall, but not for rainfall over the country as a whole. KEY WORDS Eurasian snow cover Chinese rainfall Interannual variability

No abstract

No abstract

No abstract

Peroxidase-mimetic materials are intensively applied to establish multienzyme systems because of their attractive merits. However, almost all of the nanozymes explored exhibit catalytic capacity only under acidic conditions. The pH mismatch between peroxidase mimics in acidic environments and bioenzymes under neutral conditions significantly restricts the development of enzyme–nanozyme catalytic systems especially for biochemical sensing. To solve this problem, here amorphous Fe-containing phosphotungstates (Fe-PTs) featuring high peroxidase activity at neutral pH were explored to fabricate portable multienzyme biosensors for pesticide detection. The strong attraction of negatively charged Fe-PTs to positively charged substrates as well as the accelerated regeneration of Fe2+ by the Fe/W bimetallic redox couples was demonstrated to play important roles in endowing the material with peroxidase-like activity in physiological environments. Consequently, integrating the developed Fe-PTs with acetylcholinesterase and choline oxidase led to an enzyme–nanozyme tandem platform with good catalytic efficiency at neutral pH for organophosphorus pesticide response. Furthermore, they were immobilized onto common medical swabs to fabricate portable sensors for paraoxon detection conveniently based on smartphone sensing, showing excellent sensitivity, good anti-interference capacity, and low detection limit (0.28 ng/mL). Our contribution expands the horizon of acquiring peroxidase activity at neutral pH, and it will also open avenues to construct portable and effective biosensors for pesticides and other analytes.