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This paper reports the results of radioactivity concentrations and heavy metal content in soil samples collected from non-agricultural areas in the municipality and vicinity of North Kosovska Mitrovica, formerly the most important mining area in Europe. The estimated average activity concentrations of (226)Ra, (232)Th, (40)K and (137)Cs are 40.6 ± 19, 48 ± 25.4, 743.2 ± 200.5 and 81 ± 119 Bq kg(-1), respectively. The estimated average absorbed dose rate in the air and the annual effective dose are 78.7 nGy h(-1) and 96.6 μSv, respectively. The radium equivalent activity and external hazard index were also calculated. High contents of Pb, Zn, Cu, Cd, As and Ni were found in the analyzed soil samples, thus indicating pollution of the environment. Most metals have a wide range of values spanning 2 to 3 orders of magnitude, which is particularly evident for Pb and Zn. Correlations between the activity concentrations of the radionuclides, the heavy metal content in soil and the basic soil properties were determined by means of the Pearson linear coefficient. Strong positive correlations between the naturally occurring radionuclides, and also among Pb, Zn, Cu and Cd were found.

Radioactivity concentrations and heavy metal content were measured in soil samples collected from the area of Kragujevac, one of the largest cities in Serbia. The specific activities of (226)Ra, (232)Th, (40)K and (137)Cs in 30 samples were measured by gamma spectrometry using an HPGe semiconductor detector. The average values ± standard deviations were 33.5 ± 8.2, 50.3 ± 10.6, 425.8 ± 75.7 and 40.2 ± 26.3 Bq kg(-1), respectively. The activity concentrations of (226)Ra, (232)Th and (137)Cs have shown normal distribution. The annual effective doses, radium equivalent activities, external hazard indexes and excess lifetime cancer risk were also estimated. A RAD7 device was used for measuring radon exhalation rates from several samples with highest content of (226)Ra. The concentrations of As, Co, Cr, Cu, Mn, Ni, Pb and Zn were measured, as well as their EDTA extractable concentrations. Wide ranges of values were obtained, especially for Cr, Mn, Ni, Pb and Zn. The absence of normal distribution indicates anthropogenic origin of Cr, Ni, Pb and Zn. Correlations between radionuclide activities, heavy metal contents and physicochemical properties of analysed soil were determined by Spearman correlation coefficient. Strong positive correlation between (226)Ra and (232)Th was found.

Since 1996/97, indoor radon has been measured in scattered locations around Kosovo. In the most recent campaign, apart from radon, thoron and Rn and Tn progenies have also been measured. The current survey involves 48 houses, in which different detectors have been deployed side-by-side in one room, in order to measure indoor radon and thoron gas with RADUET devices based on CR-39 detectors (analysed by Japanese collaborators) and with direct thoron and radon progeny sensor (DTPS and DRPS) devices based on LR-115 detectors (analysed by collaborators from India). Estimated arithmetic mean values of concentrations in 48 houses are 122 Bq m(-3) for radon and 136 Bq m(-3) for thoron. Those for equilibrium equivalent radon concentration and equilibrium equivalent thoron concentration based on measurements in 48 houses are 40 and 2.1 Bq m(-3), respectively. The arithmetic mean value of the equilibrium factor is estimated to be 0.50 ± 0.23 for radon and 0.037 ± 0.041 for thoron. The preliminary results of these measurements are reported, particularly regarding DTPS and DRPS being set up in real field conditions for the first time in the Balkan region. The results are to be understood under the caveat of open questions related to measurement protocols which yield reproducible and representative results, and to quality assurance of Tn and Rn/Tn progeny measurements in general, some of which are discussed.

Some previous studies on radon concentration in dwellings of some areas of Kosovo and Metohija have revealed a high average radon concentration, even though the detectors were exposed for three months only. In order to better design a larger study in this region, the annual measurements in 25 houses were carried out as a pilot study. For each house, CR-39-based passive devices were exposed in two rooms for the two consecutive six-month periods to account for seasonal variations of radon concentration. Furthermore, in order to correlate the indoor radon with radium in nearby soil and to improve the knowledge of the natural radioactivity in the region, soil samples near each house were collected and 226Ra, 232Th, 40K activity concentration were measured. The indoor radon concentration resulted quite high from the average (163 Bq/m3) and generally it did not differ considerably between the two rooms and the two six-month periods. The natural radionuclides in soil resulted to be distributed quite uniformly. Moreover, the correlation between the226Ra content in soil and radon concentration in dwellings resulted to be low (R2=0.26). The annual effective dose from radon and its short-lived progeny (5.5 mSv, in average) was calculated by using the last ICRP dose conversion factors. In comparison, the contribution to the annual effective dose of outdoor gamma exposure from natural radionuclides in soil is nearly negligible (66 mSv). In conclusion, the observed high radon levels are only partially correlated with radium in soil; moreover, a good estimate of the annual average of radon concentration can be obtained from a six-month measurement with a proper choice of exposure period, which could be useful when designing large surveys