A novel and efficient copper-catalyzed homocoupling of ketoxime carboxylates has been developed for the synthesis of symmetrical pyrroles. This reaction tolerates a wide range of functional groups and provides a synthetically useful process to synthesize valuable symmetrical pyrroles under mild conditions.
A novel and efficient palladium-catalyzed aminocarbonylation of aryl iodides with amides and N-alkyl anilines has been developed. The reaction tolerates a wide range of functional groups and is a reliable method for the rapid synthesis of a variety of valuable imides and tertiary benzanilides under an atmospheric pressure of CO.
A novel
palladium-catalyzed carbonylation of indoles with CO and
aromatic boronic acids for the synthesis of indol-3-yl aryl ketones
was developed. The reaction tolerates a wide range of functional groups
and gives a variety of valuable indol-3-yl aryl ketones in high yields
under mild conditions.
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