On the basis of the idea that the injecting energy will improve the conditions for the formation of Cooper pairs, a smart meta-superconductor (SMSC) was prepared by doping luminescent nanocomposite Y2O3:Eu3+/Ag in MgB2. To improve the superconducting transition temperature (TC) of the MgB2-based superconductor, two types of Y2O3:Eu3+/Ag, which has the strong luminescence characteristic, with different sizes were prepared and marked as m-Y2O3:Eu3+/Ag and n-Y2O3:Eu3+/Ag. MgB2 SMSC was prepared through an ex situ process. Results show that when the dopant content was fixed at 2.0 wt.%, the TC of MgB2 SMSC increased initially then decreased with the increase in the Ag content in the dopant. When the Ag content is 5%, the TC of MgB2 SMSC was 37.2–38.0 K, which was similar to that of pure MgB2. Meanwhile, the TC of MgB2 SMSC doped with n-Y2O3:Eu3+/Ag increased initially then decreased basically with the increase in the content of n-Y2O3:Eu3+/Ag, in which the Ag content is fixed at 5%. The TC of MgB2 SMSC doped with 0.5 wt.% n-Y2O3:Eu3+/Ag was 37.6–38.4 K, which was 0.4 K higher than that of pure MgB2. It is thought that the doping luminescent nanocomposite into the superconductor is a new means to improve the TC of SMSC.
of the luminescent inhomogeneous phase doping samples increased and then decreased as increasing current.Keywords smart meta-superconductor MgB2 · Y2O3:Eu 3+ nanosheets · Inhomogeneous phase·Applied electric field·TC
Improving luminescent intensity is a significant technical requirement and scientific problem for the luminescent performance of fluorophor materials through the ages. The process control and luminescence performance still limit the developments of luminescent intensity even through it can be improved partly by covering or magnetron sputtering of precious metals on the surface of the fluorophore materials. On the basis of the improvement of luminescence center radiative transition rate by surface plasma resonance and Y2O3:Eu 3+ microsheet phosphors, a fundamental model for topological luminophor Y2O3:Eu 3+ +Ag was designed referencing the concepts of topological materials in order to enhance luminescent performance by composite-luminescence, which composed of Eu 3+ centric electroluminescence and surface plasma-enhanced photoluminescence by Ag. The topological luminophor Y2O3:Eu 3+ +Ag was successfully synthesized with an asymmetric-discrete Ag nanocrystal topological structure on the surface just via illumination. Experiment results suggest that the luminescence performance of topological luminophor Y2O3:Eu 3+ +Ag increased by about 300% compared with that of Y2O3: Eu 3+ phosphors on the same conditions. The design of a topological luminophor provides a new approach to further improve the luminescent intensity of phosphors.
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