Polycyclic aromatic hydrocarbons (PAHs) are found on various planetary surfaces in the solar system. They are proposed to play a role in the emergence of life, as molecules that are important for biological processes could be derived from them. In this work, four PAHs (pyrene, perylene, anthracene, and coronene) were measured using the ORganics Information Gathering INstrument system (ORIGIN), a lightweight laser desorption ionization-mass spectrometer designed for space exploration missions. In this contribution, we demonstrate the current measurement capabilities of ORIGIN in detecting PAHs at different concentrations and applied laser pulse energies. Furthermore, we show that chemical processing of the PAHs during measurement is limited and that the parent mass can be detected in the majority of cases. The instrument achieves a 3σ detection limit in the order of femtomol mm−2 for all four PAHs, with the possibility of further increasing this sensitivity. This work illustrates the potential of ORIGIN as an instrument for the detection of molecules important for the emergence or presence of life, especially when viewed in combination with previous results by the instrument, such as the identification of amino acids. ORIGIN could be used on a lander or rover platform for future in situ missions to targets in the solar system, such as the icy moons of Jupiter or Saturn.
The detection of biomolecules on Solar System bodies can help us to understand how life emerged on Earth and how life may be distributed in our Solar System. However, the detection of chemical signatures of life on planets or their moons is challenging. A variety of parameters must be considered, such as a suited landing site location, geological and environmental processes favourable to life, life detection strategies, and the application of appropriate and sensitive instrumentation. In this contribution, recent results obtained using our novel laser desorption mass spectrometer ORganics INformation Gathering Instrument (ORIGIN), an instrument designed for in situ space exploration, are presented. We focus in this paper on the detection and identification of amino acid extracts from a natural permafrost sample, as well as in an analogue mixture of soils and amino acids. The resulting dataset was analysed using a correlation network analysis method. Based on mass spectrometric correlation, amino acid signatures were separated from soil signatures, identifying chemically different molecular components in complex samples. The presented analysis method represents an alternative to the typically applied spectra-by-spectra analysis for the evaluation of mass spectrometric data and, therefore, is of high interest for future application in space exploration missions.
The current account presents the results of a 14-day amphibian survey at Maliau Basin Conservation Area (MBCA). With a total of approximately 170 man-hrs, 44 species were detected at four study sites during the field period; four more species were later discovered outside the two-week campaign. The results are compared to the results of previous surveys. Apart from adults, we present the first photographic documentation of the larval stages ofChiromantisinexpectatusand BorneanPhrynoidisjuxtaspera, along with a brief tadpole description; the better-known tadpoles of four more species were recorded. The results of our expedition suggest that nine more species are present at MBCA than reported by previous studies. We present an updated list of known species in the MBCA, comprising 61 species. The species accumulation curve over the 14 days period of the core survey did not show signs of asymptotic saturation. We conclude that the definitive species number for MBCA amphibians has the potential to increase with more thorough surveys in the future.
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