The Birimian and Tarkwaian aquifer systems are the main sources of water supply for the Bosome Freho District and Bekwai Municipality inhabitants in the Ashanti region of Ghana. A hydrogeochemical assessment was carried out to ascertain the natural baseline chemistry of the groundwaters and the factors influencing groundwater chemistry in these two areas. A multivariate statistical tool consisting of principal component analysis (PCA) and hierarchical cluster analysis (HCA) together with hydrochemical graphical plots was applied on 64 groundwater samples. The Q–mode HCA results were used to explain the changes in groundwater chemistry along the flow paths where three spatial groundwater zones and water types were delineated. The first type consists of Ca–Mg–HCO3 freshwater (recharge zone), which transitions into Ca–Na–HCO3 or Na–Ca–HCO3 mixed waters (intermediate zone) and finally evolves to the third type of Na–Ca–Mg–HCO3–Cl water (discharge zone). The study also reveals that the natural process influencing water chemistry is groundwater–rock interaction from carbonate and silicate weathering/dissolution, aided by carbonic acid from precipitation and releases concentration of Na+, Ca2+, Mg2+, and HCO3− into the groundwaters significantly. The chloro-alkaline indices also reveal cation exchange as the principal natural factor that controls groundwater chemistry in the area. Inverse geochemical modelling shows the dissolution of primary minerals such as dolomite, plagioclase, halite, gypsum, and precipitation of calcite and chlorite along the groundwater flow path. Anthropogenic activities have little influence on groundwater chemistry. The quality of groundwater in the Bosome Freho District and Bekwai Municipality is suitable for irrigational use and drinking water consumption. The results obtained so far will contribute to research paucity in the study area and serve as a guide for decision-makers for improved water resources management.

The 'Tamnean' Plutonic Suite aquifer is the main public water supply for the Garu-Tempane District. Thus, hydrogeochemical characterization is essential to provide valuable insights into pollution sources and the main controls on groundwater chemistry. In this regard, multivariate statistical methods, conventional hydrochemical graphical methods, and various ionic ratios complemented with PHREEQC geochemical modelling were carried out using 38 groundwater samples collected from the Tamnean Plutonic Suite aquifers, Ghana. The ionic ratio plots, the chloro-alkaline indices, and the graphical diagrams indicate that the major sources of groundwater chemistry are silicate mineral dissolution and cation exchange coupled with the leaching of domestic solid waste and nitrogen-based fertilizers. The Q-mode hierarchical cluster analysis reveals three spatial groundwater zones. Groundwater from recharge areas consists of Ca–Na–HCO3 water types in cluster 1. The intermediate zone is characterized by Ca–Mg–Na–HCO3 water types of moderate ionic compositions in cluster 2, and this evolves into a discharge zone in cluster 3 mainly of Ca–Mg–Na–HCO3–NO3 water types. The principal component analysis (PCA) reveals three factors, which account for 81% of the total variance, and this suggests most of the groundwater chemistry had longer interaction with the lithological materials. The PHREEQC geochemical modelling consisting of mineral saturation index indicates that groundwater is mostly supersaturated with respect to dolomite and undersaturated with respect to calcite, anhydrite, fluorite, gypsum, and halite. Based on the water quality index, the groundwater in the district is generally suitable for drinking water purposes. All the samples are within the World Health Organization acceptable limits for drinking water except for lower pH, elevated nitrate and bromide concentrations in some of the wells. About 10.5% of the groundwater samples are contaminated with nitrate, which may pose a health danger to the inhabitants in the communities. The finding of this study will not only contribute to solving the research paucity regarding the Tamnean Plutonic Suite aquifers in the Garu-Tempane District but will serve as a valuable document for water managers and decision-makers in Ghana.

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Increasing population growth and global climatic changes threaten water security in semiarid regions such as Northern Ghana. The Tamnean Plutonic Suite aquifer is the main source of water supply for the inhabitants of the Tamne River basin, which is a transboundary subbasin of the White Volta Basin, Ghana. The basin is a flood-prone area where flooding occurs every rainy season, but there is water scarcity during the dry season, mainly due to poor groundwater resources planning. It is expected that the population will increase in the next 10 years, implying a greater water demand. A steady-state and transient groundwater flow model has been developed to understand the hydrogeological conditions and assess the feasibility of managed aquifer recharge (MAR) in the area. A single granitic aquifer formation was delineated from the three-dimensional lithology modelling. The calibrated aquifer recharge through precipitation is very low due to high evapotranspiration and low rainfall. A MAR injection scenario was tested using the available treated floodwater that is registered during the rainy season in the area. The results show the total volume of water injected at the end of the 4-month study period is 11,000 m3/day (approximately 1.3 × 106 m3), which significantly increases aquifer storage and groundwater levels. The volume of water recovered at the end of 8 months (1.4 × 106 m3) is enough for domestic and irrigation purposes during the dry season. In general, MAR is feasible in augmenting the water levels in the area when combined with controllable irrigation and domestic withdrawals.

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