The emerging wearable electronics integrated into textiles are posing new challenges both in materials and micro-fabrication strategies to produce textile-based energy storage and power source micro-devices. In this regard, inkjet printing (IJP) offers unique features for rapid prototyping for various thin-film (2D) devices. However, all-inkjet-printed capacitors were very rarely reported in the literature. In this work, we formulated a stable Ti3C2 MXene aqueous ink for inkjet printing current-collector-free electrodes on TPU-coated cotton fabric, together with an innovative inkjet-printable and UV-curable solvent-based electrolyte precursor. The electrolyte was inkjet-printed on the electrode’s surface, and after UV polymerization, a thin and soft gel polymer electrolyte (GPE) was obtained, resulting in an all-inkjet-printed symmetrical capacitor (a-IJPSC). The highest ionic conductivity (0.60 mS/cm) was achieved with 10 wt.% of acrylamide content, and the capacitance retention was investigated both at rest (flat) and under bending conditions. The flat a-IJPSC textile-based device showed the areal capacitance of 0.89 mF/cm2 averaged on 2k cycles. Finally, an array of a-IJPSCs were demonstrated to be feasible as both a textile-based energy storage and micro-power source unit able to power a blue LED for several seconds.