A promising lithium salt of Li difluorophosphate (LiPO2F2) is introduced and added to the basic electrolyte
(1
M LiPF6 + dimethyl carbonate (DMC)/ethyl methyl carbonate
(EMC)/propylene carbonate (PC)/fluoroethylene carbonate (FEC)) to
enhance the electrochemical performance of lithium-ion batteries by
changing its concentration at low temperatures. Experiments show that
LiPO2F2 can obviously improve the electrolyte’s
ionic conductivity, especially. Compared with the baseline (6.29,
5.14, 4.62, 3.77, and 3.15 mS cm–1) under the same
conditions, the ionic conductivities of the 2 wt % LiPO2F2-containing electrolyte (2 LiPO2F2) are 7.18, 5.32, 5.23, 4.04, and 3.57 mS cm–1.
From this, it is clear that the integrated low-temperature electrochemical
performances have been significantly improved. The specific discharge
capacities of the 2 wt % LiPO2F2-added electrolyte
at 0.2C are 161.4, 157.2, 148.9, and 137.5 mAh g–1 in the range from 25 to −40 °C, which are significantly
much higher compared with the basic electrolyte (145.3, 149.4, 135.1,
and 107.0 mAh g–1, respectively). Additionally,
the addition of LiPO2F2 can promote profoundly
the composition and morphology characteristics of the cathode–electrolyte
interface (CEI) film; namely, it is a uneven lithium alkyl carboxylate
before the addition of LiPO2F2; after that,
it becomes an even LiF film, and meanwhile, the new film will facilitate
Li+ transport in the electrolyte, further boosting the
eletrochemical performance of the cells under low temperatures. At
−40 °C under the same current density, the specific discharge
capacity is 81.97 mAh g–1 after 50 cycles, while
at the same temperature, the specific discharge capacity of the basic
electrolyte battery is only 33.37 mAh g–1; that
is, the discharge capacity has a staggering 145.6% improvement at
−40 °C. In conclusion, the lithium-ion batteries containing
LiPO2F2 may meet the application requirements
of ultra-low-temperature conditions.