Photoswitchable metal-organic frameworks (MOFs) enable the dynamic remote control of their key properties. Here, a readily producible approach is presented where photochromic molecules, i.e. azobenzene (AB) and o-tetrafluoroazobenzene (tfAB), are loaded in MOF films of type HKUST-1. These nanoporous films, which can be reversibly switched with UV/visible or only visible light, have remote-controllable guest uptake properties.

As in the case of other semiconducting materials, optical and electronic properties of metal-organic frameworks (MOFs) depend critically on defect densities and defect types. We demonstrate here that, in addition to the influence of imperfections on MOF chemical properties like guest binding energies and catalytic activity, the optical properties of these crystalline molecular solids also crucially depend on deviations from the perfect crystalline structure. By recording UV-vis absorption spectra for MOF thin films of particularly high quality, we demonstrate that low-defect samples of an important MOF, HKUST-1, are virtually colorless. Electronic structure calculations of the excited states by employing complete active space self-consistent field (CASSCF) calculations show that the d-d excitations in defects result in the typical green color of the MOF material synthesized by conventional methods.

Performance-limiting surface defects in metal–organic frameworks caused by exposure to a humid environment can be dissolved by exposure to ethanol.

The formation of gold nanoparticles in the first 2–20 ms of the reaction was studiedin situwith XAS using microfluidics.

A 'lawn-like' distribution of interconnected zinc oxide nanorods, coated with a metalorganic compound based on zeolitic imidazolate frameworks-ZIF-8 was prepared on microstructured thin-film interdigitated Pt-electrodes forming ZnO@ZIF-8 core-shell heterostructures and investigated as gas sensor material in relation to the identical, but uncovered pure ZnO-layer. This composite combines the gas sensing properties of the metal oxide ZnO with the specific properties of the metal organic framework material which result in a distinct change of the conditions of gas sensing at the ZnO/ZIF-8-interface. Herein, for the first time it is reported that as prepared ZnO@ZIF-8 composite material is an attractive choice to reduce the cross-sensitivity to water vapour (humidity) in the gas sensing response towards propene and ethene. The observed change of sensitivity in relation to uncovered ZnO is discussed to be due to (i) the specific interaction of the ZIF-8 at the interface with the ZnO taking influence on the gas reaction processes, (ii) the diffusivity of ZIF-8 for the different gas components, and (iii) the sorption behaviour of the used gases at the ZnO interface and inside the ZIF-8 material.