Lubricants have much importance in several industries, principally serving to reduce friction and wear in mechanical elements. In this study, the influence of Castor oil as bio-lubricant on the friction and wear performance of AISI 4140 steel was investigated. For that purpose, pin-on-disk friction tests were conducted according to ASTM G-99, by using pins of tungsten carbide (WC) as counterparts. The experiments were performed at two different temperatures. This work also presents the Attenuated Total Reflection Fourier Transform Infrared Spectroscopy (ATR-FTIR) and 1 H-NMR analyses for the chemical characterization of oils and a study of their degradation by oxidation. The analysis of the damage caused to steel due to friction was deepened by analyzing its microhardness and microstructure in the worn zone. As a reference, the same experiments were performed with a commercial oil. The friction behavior of 4140 steel/WC with Castor oil lubrication at the two temperatures was notably better than that obtained under the reference oil lubrication. The kinetic friction coefficient (µ k) was up to 76% lower. However, a slight increase in steel wear was observed under Castor oil lubrication. Despite this, these results suggest that Castor oil could be used as bio-lubricant in systems which are susceptible to levels of high friction.
Although much has been learned and investigated about environmentally friendly lubricants in recent years, several issues remain critical to their use in specific applications. A key point that could be limiting their utilization is that the effect of green lubricants on the tribological and mechanical properties of the elements has not been thoroughly studied since such attributes determine their performance in industrial applications. For this reason, in this research, the effect of green lubrication on the tribological and hardness properties of AISI 4140 steel was studied. The performance of three bio-based lubricants was studied and compared to that of five of the most representative lubricants. First, the lubricants were chemically and physically characterized. Then, the effect of each lubricant on the friction and wear behavior of the system was analyzed by kinetic friction coefficient, wear rate calculations, and microhardness measurements. In general, the bio-based lubricants exhibited the lowest values of friction and wear. Further the mechanical properties of the systems lubricated by these lubricants were not affected or were affected to a lesser degree.
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