No abstract

Tauc-Lorentz model is commonly used to describe the dielectric constant of amorphous semiconductors as a function of few parameters. However, this model is not fully analytic and presents other mathematical shortcomings. A modified self-consistent model based on the integration of [E'-(E + ia)]-1 functions using Tauc-Lorentz`s ε2 expression as a weight function is presented. This new model is analytic and meets all other mathematical requirements of optical constants. The main difference with TL model stands at photon energies close to or smaller than the bandgap energy. The new model has been satisfactorily tested on SiC optical constants. Additionally, an analytic extension of the new model has been also developed to include the Urbach tail. The complete model has been tested with Si₃N₄ optical constants, and it enables to extend the optical-constant characterization of materials down to zero energy.

Sum rules are a useful tool to evaluate the global consistency of a set of optical constants. We present a procedure to spectrally tune sum rules to evaluate the local consistency of optical constants. It enables enhancing the weight of a desired spectral range within the sum-rule integral. The procedure consists in multiplying the complex refractive index with an adapted function, which is named window function. Window functions are constructed through integration of Lorentz oscillators. The asymptotic decay of these window functions enables the derivation of a multiplicity of sum rules akin to the inertial sum rule, along with one modified version of f-sum rule. This multiplicity of sum rules combined with the free selection of the photon energy range provides a double way to tune the spectral contribution within the sum rule. Window functions were applied to reported data of SrF2 and of Al films in order to check data consistency over the spectrum. The use of window functions shows that the optical constants of SrF2 are consistent in a broad spectrum. Regarding Al, some spectral ranges are seen to present a lower consistency, even though the standard sum rules with no window function did not detect inconsistencies. Hence window functions are expected to be a helpful tool to evaluate the local consistency of optical constants.

No abstract