The hypoeutectic aluminum alloy AlSi5Cu2Mg is used for the production of high-strength cylinder head castings. The alloy is unique for its specific low permitted Ti content (0.03 wt% max), which makes it impossible to refine the grain structure of this alloy using standard Al–Ti–B grain refiners. The specific chemical composition is specified by the supplier company. The aim of this paper is to find a suitable alloying element that would improve the selected properties (e.g., mechanical, and physical properties) that are crucial for cylinder head castings. The research focuses on the investigation of the effect of different Zr addition (0.05; 0.10; 0.15 and 0.20 wt% Zr in the form of AlZr20 master alloy) on the properties of AlSi5Cu2Mg in the as-cast state and after heat treatment T7. The obtained results showed that ultimate tensile strength, yield strength, hardness, and physical properties of as-cast samples do not change significantly with increasing Zr content. The experimental alloys showed a more significant increase in ultimate tensile strength, yield strength, hardness, and thermal conductivity after heat treatment T7. Zirconium-rich intermetallic phases were observed in the shape of separate thick needles or as a cluster of two crossed thinner needles.
The aim of this paper was to analyze the impact of the addition of different amounts of zirconium (0.05; 0.10; 0.15 and 0.20 wt. % Zr in the form of the AlZr20 master alloy) on selected properties of AlSi5Cu2Mg aluminum alloy. This is a new alloy for cylinder head castings and has only been used for a relatively short time. The specificity of this alloy is its chemical composition—specifically the low permitted Ti content, which makes it impossible to refine the grain structure of this alloy using standard Al-Ti-B grain refiners. The aim of our ongoing research is to find a suitable alloying element that would positively mainly affect the mechanical and also physical properties of this alloy, which are crucial for complex automotive castings such as cylinder heads. The results of our research showed that increasing zirconium content had no effect on the increase in ultimate tensile strength, yield strength and hardness of as-cast samples. After T7 heat treatment, a more significant increase in UTS, YS and thermal conductivity occurred due to the precipitation of Cu- and Mg-rich strengthening precipitates. Zirconium-rich intermetallic phases were observed in the shape of separate thick needles or as a cluster of two crossed thinner needles. SEM observations showed that these phases crystallized near to the intermetallic phases based on Cu and Fe. Increasing the Zr content was accompanied by an increase in liquidus temperature, the density index and the area fraction of porosity values.
The main reason for the use of returnable material, or recycled alloys, is a cost reduction while maintaining the final properties of the casting. The casting resulting quality is directly related to the correct ratio of commercial grade alloy and alloy made by remelting the returnable material in the batch. The casting quality is also affected by the purity of the secondary raw materials used, the shape complexity and the use of the casting itself. The presented article focuses on the effect of increasing the returnable material content in the batch on the hot tearing susceptibility of AlSi9Cu3 alloy. Hot tears are a complex phenomenon that combines metallurgical and thermo-mechanical interactions of the cast metal. Hot tearing susceptibility was evaluated on the basis of quantitative (HTS—hot tearing susceptibility index) and qualitative evaluation. The negative effect of returnable material in the batch was already manifested at a 20% content in the batch. The critical proportion of the returnable alloy in the batch can be stated as 50%. The alloy with a 50% returnable material content manifested insufficient results of the HTS index and qualitative evaluation, which means increased sensitivity to tearing. The negative effect of returnable material and the increased sensitivity were also confirmed in the evaluation of the fracture surface and hot tear profile. The microstructure of alloys with 50% and higher proportion of returnable material was characterized by a higher amount of iron phases (mainly Al5FeSi), whose sharp ends acted as critical regions of hot tearing and subsequent hot tear propagation, which had a major impact on the increase in hot tearing susceptibility.
The aim of this paper was to analyze the impact of varying zirconium additions (0.05; 0.10; 0.15 and 0.20 wt. % Zr) on corrosion behavior of the AlSi5Cu2Mg aluminum alloy. Potentiodynamic polarization corrosion tests in 3.5 % NaCl solution demonstrated that the addition of Zr improved the thermodynamic corrosion stability of the AlSi5Cu2Mg alloy by shifting the corrosion potential to more positive values for all as-cast samples. The addition of Zr to the as-cast alloys also improved corrosion kinetics by lowering the corrosion current density.
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