By triple condensation of 2-allylphenol with formaldehyde and methylamine (at a ratio of 1:1:1 and 1:2:1 mol, at 800C for 3 hours) a number of compounds (I-III) of various structures was prepared. It has been established that, depending on the ratio of the taken reagents, compounds of various structures are formed. By the reaction of compound I - 8-allyl-substituted 1,3-benzoxazine with HBr quaternary ammonium salt (IV) was obtained. Antimicrobial activity of 8-allyl-substituted 1,3-benzoxazine (I) and ammonium salt (IV) against microorganisms: Staphylococcus aureus NCTC 6571, Staphylococcus aureus ATCC®25923, Escherichia coli ATCC®25922, Candida albicans NSTC-3255/ATCC2091, Shigella flexneri ATCC®12022, Salmonella enterica ATCC®13076, and Aspergillus niger (aquatic isolate) was studied. It was found that compounds I and IV at a concentration of 30 mg/L in comparison with the references (amoxicillin and fluconazole) have the highest bactericidal and fungicidal properties. By thermal treatment of compound I cross-linked copolymer V was synthesized. While studying the thermal properties of copolymer V their sufficient thermal stability (up to ~4500C) was established. Copolymer V also has a sorption property for the extraction of uranyl ions from aqueous systems (the degree of extraction at pH 7 is ~70%, the sorption capacity – 178 mg/g). The structures of the obtained compounds were confirmed by IR and NMR spectroscopy
. The article presents the results of studies on the evaluation of the adsorption properties of three aromatic compounds containing simultaneously several active centers in the structures - fragments with double and triple bonds and an aminomethyl group: 1-propenyl-2-propargyloxy-3-diethylaminomethylbenzene (I), 1-allyl- 2-propargyloxy-3-diethylaminomethylbenzene (II) and 1-allyl-2-propargyloxy-3-morphoaminomethylbenzene (III). Based on the data of gravimetric studies, the adsorption-desorption constants (Kads), as well as the adsorption energy (Gads) were calculated, confirming the mechanism for protecting the steel surface from acid corrosion by forming chemisorbed adsorption layers on it.
The article presents the results of three-component condensation of 4-isopropenylphenol, formaldehyde and 4-(1-methyl)-1-dimethoxsiphosphorylethyl)phenol cooligomers, their structuring with acrylonitrile. In order to include the carboxyl group in the structure of the cross-linked copolymer, hydrolysis was carried out in the presence of an aqueous solution of potassium hydroxide. The process of sorption of uranyl ions from model aqueous systems by structured (crosslinked) with acrylonitrile and their product of hydrolyze. The structure of the cross-linked copolymer was confirmed by IR spectroscopy data. It has been established that the process of sorption of uranyl ions is significantly affected by the pH of the medium. The best results in the extraction of uranyl ions by the sorbent are achieved at pH 7–8 (at room temperature, the degree of their sorption is ~89–93%, and SCS is ~229–239 mg/g). It has been established that the process is completed within 24 hours, cross-linked co-oligomers can be reused after desorption of uranyl ions by mineral acids
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