As synthesised ZIF-8 nanoparticles (size $ 60 nm and specific surface area $ 1300-1600 m 2 g À1 ) were directly incorporated into a model polymer matrix (MatrimidÒ 5218) by solution mixing. This produces flexible transparent membranes with excellent dispersion of nanoparticles (up to loadings of 30 wt%) with good adhesion within the polymer matrix, as confirmed by scanning electron microscopy, dynamic mechanical thermal analysis and gas sorption studies. Pure gas (H 2 , CO 2 , O 2 , N 2 and CH 4 ) permeation tests showed enhanced permeability of the mixed matrix membrane with negligible losses in selectivity. Positron annihilation lifetime spectroscopy (PALS) indicated that an increase in the free volume of the polymer with ZIF-8 loading together with the free diffusion of gas through the cages of ZIF-8 contributed to an increase in gas permeability of the composite membrane. The gas transport properties of the composite membranes were well predicted by a Maxwell model whilst the processing strategy reported can be extended to fabricate other polymer nanocomposite membranes intended for a wide range of emerging energy applications.

Studies of the spin and parity quantum numbers of the Higgs boson are presented, based on proton–proton collision data collected by the ATLAS experiment at the LHC. The Standard Model spin–parity JP=0+JP=0+ hypothesis is compared with alternative hypotheses using the Higgs boson decays H→γγH→γγ, H→ZZ⁎→4ℓH→ZZ⁎→4ℓ and H→WW⁎→ℓνℓνH→WW⁎→ℓνℓν, as well as the combination of these channels. The analysed dataset corresponds to an integrated luminosity of 20.7 fb−1 collected at a centre-of-mass energy of √s=8TeV. For the H→ZZ⁎→4ℓH→ZZ⁎→4ℓ decay mode the dataset corresponding to an integrated luminosity of 4.6 fb−1 collected at √s=7TeV is included. The data are compatible with the Standard Model JP=0+JP=0+ quantum numbers for the Higgs boson, whereas all alternative hypotheses studied in this Letter, namely some specific JP=0−,1+,1−,2+JP=0−,1+,1−,2+ models, are excluded at confidence levels above 97.8%. This exclusion holds independently of the assumptions on the coupling strengths to the Standard Model particles and in the case of the JP=2+JP=2+ model, of the relative fractions of gluon-fusion and quark–antiquark production of the spin-2 particle. The data thus provide evidence for the spin-0 nature of the Higgs boson, with positive parity being strongly preferre

Proton-proton collisions at √ s = 7 TeV and heavy ion collisions at √ s NN = 2.76 TeV were produced by the LHC and recorded using the ATLAS experiment's trigger system in 2010. The LHC is designed with a maximum bunch crossing rate of 40 MHz and the ATLAS trigger system is designed to record approximately 200 of these per second. The trigger system selects events by rapidly identifying signatures of muon, electron, photon, tau lepton, jet, and B meson candidates, as well as using global event signatures, such as missing transverse energy. An overview of the ATLAS trigger system, the evolution of the system during 2010 and the performance of the trigger system components and selections based on the 2010 collision data are shown. A brief outline of plans for the trigger system in 2011 is presented.

The jet energy scale (JES) and its systematic uncertainty are determined for jets measured with the ATLAS detector using proton–proton collision data with a centre-of-mass energy of  TeV corresponding to an integrated luminosity of . Jets are reconstructed from energy deposits forming topological clusters of calorimeter cells using the anti- algorithm with distance parameters or , and are calibrated using MC simulations. A residual JES correction is applied to account for differences between data and MC simulations. This correction and its systematic uncertainty are estimated using a combination of in situ techniques exploiting the transverse momentum balance between a jet and a reference object such as a photon or a boson, for and pseudorapidities . The effect of multiple proton–proton interactions is corrected for, and an uncertainty is evaluated using in situ techniques. The smallest JES uncertainty of less than 1 % is found in the central calorimeter region () for jets with . For central jets at lower , the uncertainty is about 3 %. A consistent JES estimate is found using measurements of the calorimeter response of single hadrons in proton–proton collisions and test-beam data, which also provide the estimate for  TeV. The calibration of forward jets is derived from dijet balance measurements. The resulting uncertainty reaches its largest value of 6 % for low- jets at . Additional JES uncertainties due to specific event topologies, such as close-by jets or selections of event samples with an enhanced content of jets originating from light quarks or gluons, are also discussed. The magnitude of these uncertainties depends on the event sample used in a given physics analysis, but typically amounts to 0.5–3 %.

The luminosity calibration for the ATLAS detector at the LHC during pp collisions at in 2010 and 2011 is presented. Evaluation of the luminosity scale is performed using several luminosity-sensitive detectors, and comparisons are made of the long-term stability and accuracy of this calibration applied to the pp collisions at . A luminosity uncertainty of is obtained for the 47 pb−1 of data delivered to ATLAS in 2010, and an uncertainty of is obtained for the 5.5 fb−1 delivered in 2011.