We investigated the potential of an electron-beam post-treatment to tailor the properties of 70/30 and 80/20 wt. extruded starch-lignin films. The effect of a 400 kGy radiation on films differing essentially by the kind of lignins incorporated (lignosulfonates/alkali lignins) was assessed both at the macroscopic and the molecular levels. Changes in the polymer molecular structure were studied by IR spectroscopy, by thioacidolysis as well as by model compound experiments. Electron beam-irradiation at 400 kGy, a rather high dose for processing natural polymers, alters to some extent the mechanical resistance of the starch-based materials. However this treatment substantially reduces the hydrophilic surface properties of the films, while not harming their biodegradability. Involved in radical cross-coupling reactions, lignin phenolic compounds are likely to play a primary role in the formation of a hydrophobic condensed network. This study suggests that lower irradiation doses might yield biomaterials with improved usage properties.

A growth key for use in winter linseed Linum usitatissimum is described. The decimal key is based upon the principles outlined by the BBCH scale. This scale covers the following main development stages in winter linseed: germination and emergence, leaf development, basal branching, stem extension, inflorescence development and emergence, flowering and capsule formation, development of the seed and capsule, capsule and seed ripening and stem senescence. These are subdivided into secondary stages. The key aims to provide farmers and advisers with clear guidance on appropriate growth stages for treatment of winter linseed crops and its' use is discussed with particular reference to agro-chemicals. Botanical illustrations are presented, based on samples taken from winter linseed crops covering the main growth stages.

The recovery of nitrogen (N) from, and the fertilizer‐N value of, low dry‐matter (DM) cattle slurry and farm yard manure (FYM), applied annually to perennial ryegrass swards grown at two sites, on sandy loam and shallow calcareous silty clay loam soils, were studied over a 4‐year period. Slurry or FYM, applied at target rates of either 150 kg N ha−1 or 300 kg N ha−1 in either October, February or May/June, in combination with 150 kg N ha−1 inorganic fertilizer‐N (applied as split dressings before the first and second grass cut), were compared with a set of inorganic fertilizer‐N response treatments. DM yield, N offtake, apparent manure‐N recovery (in herbage) and manure‐N efficiency (compared with inorganic fertilizer‐N) were determined at two silage cuts each summer. Soil mineral nitrogen (SMN) measurements in autumn and spring were used to assess potential N leaching loss over winter and to quantify available N residues in the soil in spring. Apparent manure‐N recovery and manure‐N efficiency were usually greater from slurry applications in February than from those in October, but the timing of the application of FYM had a much smaller effect, compared with the timings of the application of slurry, on the utilization of N from manure by grass. Spring assessment of SMN was useful in quantifying available N residues from October slurry applications. Manure‐N recovery for all application timings was, on average, higher from the sandy loam than the shallow calcareous clay loam. The application of slurry to grass in early spring, at a rate of 150 kg total N ha−1, with the addition of a supplementary 50 kg inorganic fertilizer‐N ha−1, was the most suitable strategy for utilizing slurry‐N effectively and for supplying the N requirement for first‐cut silage.

S U M M A R YThree experiments carried out at Bridget's Experimental Husbandry Farm, Hampshire between 1984 and 1987 on clay loam and silty clay loam soils over chalk investigated the response of winter wheat grown after grass to spring-applied fertilizer nitrogen. The influence of method of establishment and the use of a nitrification inhibitor were also studied. Yields were similar whether the crops were established by direct drilling or following ploughing. Crops required between 88 and 209 kg N/ha nitrogen fertilizer for optimum yield. There was no consistent difference in nitrogen requirement nor were there consistent differences in nitrogen offtake (which is the amount of N in kg/ha removed in harvested grain) or apparent fertilizer recovery following ploughing or direct drilling. The use of a nitrification inhibitor increased grain yield when applied in the autumn without fertilizer, but not when applied with fertilizer in the spring.

The effect of nitrogen and a plant growth regulator regime (chlormequat chloride followed by 2-chloroethylphosphonic acid) on the crop performance of a hybrid (cv. Luchs) and a conventionally bred winter rye (cv. Sentinel) were investigated in two field experiments each year between 1993 and 1995 at Winchester, UK. Internode length and dry weight\unit length of internodes was measured in order to assess the effect of the growth regulator regime on stem structure. Grain yields were 15 % higher in the hybrid Luchs than in Sentinel. With high levels of applied nitrogen, both cultivars lodged in all seasons and this was most severe in 1994 when 88 % of the crop lodged in Sentinel and 52 % in Luchs. Plant growth regulator treatment consistently reduced lodging but did not eliminate it. Reductions in lodging were not always associated with an increase in grain yield. In the hybrid cultivar, the growth regulator treatment reduced yield in 1993 and 1995 when 2-chloroethylphosphonic acid was applied at GS49 and GS39 respectively, but increased yield in 1994 when applied at GS37. Growth regulator consistently reduced stem length, and the percentage reduction in length of the individual internodes within the stem was strongly influenced by the timing of the 2-chloroethylphosphonic acid component of the PGR treatment. Growth regulator reduced internode lengths by up to 25 % in Sentinel and 35 % in Luchs, and this was associated with reductions in the dry weight of internodes by up to 32 % in Sentinel and 38 % in Luchs. Consequently, dry weight\unit length of the stem was not increased by growth regulator treatment. Yield reductions in Luchs following growth regulator treatment may have been due to reduced stem reserves which have been associated with tolerance of stress in rye. Both cultivars were highly responsive to nitrogen. Economic optima varied from season to season, but they ranged over three years, from 175-273 kg\ha nitrogen, and were greater than the currently recommended application rates. Crop lodging increased with increasing nitrogen rate even when plant growth regulator was applied and yield penalties from lodging would have been high, if weather conditions during grain maturity had been unfavourable.