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A comparison of durability estimations based on mercury porosimeter data and experimental salt crystallization tests carried out on Bateig Stone from Alicante, Spain, establish that the main factor in the salt crystallization durability test is the 'ink bottle' pore system, identified by the presence of residual mercury in large pores after porosity testing. In addition, the results suggest that the commonly used indirect durability tests may not be considered a scientific definition of building stone behaviour.

Please cite this article as: Benavente, D., Pla, C., Cueto, N., Galvañ, S., Martínez-Martínez, J., García-del-Cura, M.A., Ordóñez, S., Predicting water permeability in sedimentary rocks from capillary imbibition and pore structure, Engineering Geology (2015), AbstractIn this paper, absolute water permeability is estimated from capillary imbibition and pore structure for 15 sedimentary rock types. They present a wide range of petrographic characteristics that provide degrees of connectivity, porosities, pore size distributions, water absorption coefficients by capillarity and water permeabilities. A statistical analysis shows strong correlations among the petrophysical parameters of the studied rocks. Several fundamental properties are fitted into different linear and multiple expressions where water permeability is expressed as a generalized function of the properties. Some practical aspects of these correlations are highlighted in order to use capillary imbibition tests to estimate permeability. The permeability-porosity relation is discussed in the context of the influence of pore connectivity and wettability. As a consequence, we propose a generalized model for permeability that includes information about water fluid rate (water absorption coefficient by capillarity), water properties (density and viscosity), wetting (interfacial tension and contact angle) and pore structure (pore radius and porosity). Its application is examined in terms of the type of pores that contribute to water transport and wettability. The results indicate that the threshold pore radius, in which water percolates through rock, achieves the best description of the pore system. The proposed equation is compared against Carman-Kozeny's and KatzThompson's equations. The proposed equation achieves very accurate predictions of the water permeability in the range of 0.01 to 1000 mD. Highlights -Permeability expressions are obtained using open porosity and capillary coefficients.-The permeability -porosity relationship shows two zones defined by a porosity of 10%.-A generalized model for predicting intrinsic permeability is proposed.-The analysis of wetting reveals incomplete water wetting in the studied rocks.