Dedolomitization of a dolocrete profile hosted in Mio-Pleistocene siliciclastic deposits in the area of Kuwait City, Arabian Gulf was investigated. Dolocrete dolomite crystals vary considerably in size, shape and internal structure; however, they are mostly zoned. Zonation is usually due to the alteration of cloudy and clear zones. The cloudy zones, which are mostly formed of disordered metastable dolomite, are more susceptible to dedolomitization than the stable, well ordered clear zones. Two modes of dedolomitization were recognized; the first involves complete dissolution of the metastable dolomite followed by precipitation of intracrystalline cavity-filling calcite. The second is a pseudomorphic replacement of dolomite by calcite. This replacement takes place by the simultaneous dissolution of dolomite and precipitation of calcite in such a manner that the original dolomite fabrics are inherited in the dedolomite. Exposed and near-surface dolocrete profile (less than 5 m deep) are almost completely dedolomitized and altered to secondary calcrete whereas subsurface profiles are slightly dedolomitized. Dedolomitization of the sub surface dolocrete profiles may indicate the effect of flushing by fresh groundwater; which flows from west to east, whereas the alteration of the exposed dolocrete profile could be attributed to be an effect of meteoric water. A new mode of calcrete genesis by dedolomitization and/or complete calcitization of precursor dolocrete is suggested.

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Soil microorganisms were not inhibited by mixing oily sludge in soil up to 8.7% (w/w) oil (15% sludge). Adding NH 4 (+) and phosphate increased microbial activity. Microbial activity was also affected by seasonal variation. Thermotolerant microorganisms were more predominant during the summer. After 29 months, 72%, 84%, and 83% of the soil was degraded in fertilized soils dosed with 2.9, 5.8 and 8.7% oil, respectively.

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