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Knowledge of alkaline silicate solutions is crucial in order to optimize geopolymer properties. Geopolymers are new binders resulting from the activation of an aluminosilicate by an alkaline solution. It is well established that the solution reactivity strongly affects the geopolymerization and therefore the geopolymer working properties. As a consequence, an evaluation of the reactivity degree of alkaline silicate solutions prior synthesis is of the utmost interest. However, the determination of the solution reactivity is currently tedious, and for geopolymer commercialization, it would be necessary to find an easy way to determine it. Therefore, Raman spectroscopy, combined with chemometric techniques, is proposed as a solution to easily determine the alkaline silicate solution reactivity. To conduct this investigation, 65 silicate solutions were characterized by Raman spectroscopy, and reference values of their reactivity degree were determined. Finally, principal component analysis and partial least squares regression were performed to build a statistical model able to predict the alkaline silicate solution reactivity from Raman spectra.