A new Ni-base superalloy VDM-780 Premium was developed for higher service temperatures (above 650°C), keeping the good processing characteristics of alloy 718. This article presents, for the first time, the morphology and the microstructure characterization of this newly developed superalloy VDM-780 by means of scanning electron microscopy (SEM) and neutron and X-ray diffraction (XRD), after three different aging treatments performed for setting up different microstructures. Results show the presence of the c-matrix, c¢-hardening phase, and a high-temperature phase whose structure is compatible with d and g phases but whose exact crystal structure or the possibility of two different high-temperature phases still remains open. Rietveld refinements have allowed phase identification, determination of the lattice constants, and the weight fractions of constituting phases and shown that the presence of the different phases, amount, and morphology highly depend on the aging treatments. No traces of the c¢¢ phase are observed regardless of the heat treatment. In situ neutron diffraction (ND) studies at high temperature have allowed the determination of the solvus temperatures of the different phases present in each material after the corresponding aging treatment as well as the study of the evolution of their lattice parameters with temperature. The Vickers hardness (HV) of the three different samples was measured, and the results are correlated with the amount and particle size of the c¢-hardening phase of each sample.

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VDM 780 Premium is a recently developed Ni-based superalloy designed for working at high service temperatures (above 650 C) while keeping the good workability of alloy 718. VDM 780 Premium is based on the austenitic matrix (g phase) strengthened by intermetallic Ni 3 Al-like precipitates (g' phase, fcc L1 2 structure). Other co-precipitates may be formed in function of the applied heat treatment, such as Ni 3 Nb-based (d phase, orthorhombic DO a structure) or Ni 3 Ti-based (h phase, hexagonal DO 24 structure) precipitates. The amount as well as the size and morphology of the different precipitates depend on the heat treatments performed on the alloy, playing an important role in improving the creep properties or the behavior during forging and recrystallization. This work contains a complex study using various techniques of analytical electron microscopy and synchrotron diffraction intended to clarify the structure of the high-temperature phase formed in the newly developed VDM 780 Premium alloy. The atomic structure of the high-temperature plate-like precipitates formed in VDM 780 Premium after two different thermal treatments has been investigated in relation with the surrounding matrix lattice, proving the stacked d/h structure of the precipitates.

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