This paper presents a review, based on the published literature and on the authors’ own research, of the current state of the art of fiber-optic capillary sensors and related instrumentation as well as their applications, with special emphasis on point-of-care chemical and biochemical sensors, systematizing the various types of sensors from the point of view of the principles of their construction and operation. Unlike classical fiber-optic sensors which rely on changes in light propagation inside the fiber as affected by outside conditions, optical capillary sensors rely on changes of light transmission in capillaries filled with the analyzed liquid, which opens the possibility of interesting new applications, while raising specific issues relating to the construction, materials and instrumentation of those sensors.
This paper presents the construction and working principles of an intelligent fiber-optic intensity sensor used for examining the concentration of a mixture in conjunction with water. It can find applications e.g. in waste-water treatment plant for selection of a treatment process. The sensor head is the end of a large core polymer optical fiber, which constitutes one arm of an asymmetrical coupler. The head works on the reflection intensity basis. The reflected signal level depends on the Fresnel reflection from the air and from the mixture examined when the head is immersed in it. The sensor head is mounted on a lift. For detection purposes the signal can be measured on head submerging, submersion, emerging and emergence. Therefore, the measured signal depends on the surface tension, viscosity, turbidity and refraction coefficient of the solution. The signal coming from the head is processed electrically in an opto-electronic interface. Then it is fed to a neural network. The novelty of the proposed sensor lies in that it contains an asymmetrical coupler and a neural network that works in the generalization mode. The sensor resolution depends on the efficiency of the asymmetrical coupler, the precision of the opto-electronic signal conversion and the learning accuracy of the neural network. Therefore, the number and quality of the points used for the learning process is very important. By way of example, the paper describes a sensor intended for examining the concentration of liquid soap in water.
Diesel fuel quality can be considered from many different points of view. Fuel producers, fuel consumers, and ecologists have their own ideas. In this paper, a sensor of diesel fuel quality type, and fuel condition that is oriented to the fuel’s consumers, is presented. The fuel quality types include premium, standard, and full bio-diesel classes. The fuel conditions include fuel fit for use and fuel degraded classes. The classes of fuel are connected with characteristics of engine operation. The presented sensor uses signal processing of an optoelectronic device monitoring fuel samples that are locally heated to the first step of boiling. Compared to previous works which consider diesel fuel quality sensing with disposable optrodes which use a more complex construction, the sensor now consists only of a capillary probe and advanced signal processing. The signal processing addresses automatic conversion of the data series to form a data pattern, estimates the measurement uncertainty, eliminates outlier data, and determines the fuel quality with an intelligent artificial neural network classifier. The sensor allows the quality classification of different unknown diesel fuel samples in less than a few minutes with the measurement costs of a single disposable capillary probe and two plugs.
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