The application of high-temperature superconducting ceramics in magnet technology and power engineering is currently limited by the difficulty of fabricating wires and precision components with the required ceramic microstructure. The results of a detailed study of the reaction process for the fabrication of large bulk artefacts of BizSrzCaCu20w by composite reaction texturing are reported. A composite preform seeded with an aligned distribution of MgO fibres is prepared by elastomer processing or by tape casting, and reacted in three stages. The first stage is binder bum-off carried out in air; the optimum heating sequence d6pendS on sample cross-section, and results in complete removal of the binder system without the introduction of macroscopic defects. The second stage involves densification in a pure oxygen atmosphere to > 96% theoretical density, followed by partial melting and slow cooling. Finally, after the preparation of suitable current contacts, the oxygen stoichiometry, critical current density and irreversibility field are optimized by post-reaction annealing in a IOW partial pressure of oxygen. The process described enables the reproducible fabrication of textured composite conductors of arbitraly shape wihcharacteristic dimensions ranging from 0.5 mm to 200 mm. The critical current density in optimized conductors is 5 x lo4 A cm-' at 5 K and 12 T, and at 77 K has a self-field limited value which is in excess of 3 x lo3 A cnr2 in small cross-section samples.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.