The wave vector dependence of Rayleigh and higher order Sezawa elastic waves in single crystalline epitaxial face-centered-cubic (fcc) Co layers are measured by Brillouin light scattering at room temperature. The dispersion of the mode velocities allows the independent elastic constants to be determined for this cubic phase of cobalt. These results compare very favorably to previous determinations of the elastic constants measured above 700 K from the high-temperature fcc phase of pure Co. Deviations from theoretical estimates are discussed.
We report experimental as well as theoretical evidence for the occurrence of a high-frequency acoustic excitation, identified as a longitudinal guided mode, in elastically hard films supported on a soft substrate. While existence criteria related to the transverse and longitudinal sound velocities in the film and substrate argue for strong decay channels into the substrate, the excitation is evident as a clear peak in the Brillouin light scattering spectra. A Green's function formalism accounts for the existence of this excitation and provides insight into its properties as illustrated for diamond-like-carbon layers deposited on silicon.
Thin amorphous films of ZrB3 grown on Si(111) substrates by chemical-vapor deposition are, upon annealing at 960 °C, transformed to films composed of nanocrystallites (6–10 nm extent) with a nominal composition of Zr0.9Si0.3B3. The independent elastic constants of the layers are determined from the dispersion of the surface and pseudo-Sezawa acoustic excitations and reveal large enhancements in the C11 and C44 constants accompanying the conversion of ZrB3 to the nanocrystalline phase. Since the transverse sound velocities of the binary and Zr0.9Si0.3B3 are in near resonance with the sound velocity of Si (VTSi=4.8 km/s), only the Rayleigh surface wave is localized to the film while all higher-order acoustic modes are evanescent. Despite the strong decay channels, high-lying excitations with velocities as large as 25 km/s (≫VTSi) are observed in Brillouin light scattering. Insight into these acoustic properties is provided by evaluating the elastodynamic Green’s functions and associated acoustic-mode densities.
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