Metal organic framework (MOF)-derived Co-doped nickel selenide/C hybrid nanostructure supported on Ni foam can efficiently catalyze the overall water splitting.

In this work, we demonstrate that the electrocatalytic activity of transition metal chalcogenides can be greatly enhanced by simultaneously engineering the active sites, surface area, and conductivity. Using metal-organic frameworks-derived (Ni,Co)Se2/C hollow rhombic dodecahedra (HRD) as a demonstration, we show that the incorporation of Ni into CoSe2 could generates additional active sites, the hierarchical hollow structure promotes the electrolyte diffusion, the in-situ hybridization with C improves the conductivity. As a result, the (Ni,Co)Se2/C HRD exhibit superior performance toward the overall water-splitting electrocatalysis in 1 M KOH with a cell voltage as low as 1.58 V at the current density of 10 mA cm-2 , making the (Ni,Co)Se2/C HRD as a promising alternative to noble metal catalysts for water splitting.

No abstract

No abstract

No abstract