The importance of the quantum chemical method and thermal decomposition kinetics on double-base propellant was reviewed. The main analysis methods and theory mode of thermal decomposition kinetics were enumerated and analyzed. It is significant to put quantum chemical method and thermal decomposition kinetics together on thermal decomposition of energetic materials especially double-base propellant. That provide science basis for safe function assesses of the propellant. It provides science basis for the forecast of service life and the evaluation of security.
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