The negative impact of high concentrations of lead in the analytical environment on humans and aquatic plants prompted this research. The adsorption of hazardous lead from an aqueous medium using a Modified Doum Palm (MDP) shell was investigated. The modification of the Doum palm shell was supported via 2 M 1: 2 ZnCl2 as activating agent. The batch equilibrium technique was employed to study the effect of initial concentration (800 mg/L), contact time (90 min) and temperature (313 K) on the adsorption capacity of the prepared adsorbent. Experimental data were analyzed using four kinetic models: pseudo-first-order, pseudo-secondorder, intra-particle diffusion and Elovich models and it was found that the pseudo-second-order model fitted the adsorption data most with the highest correlation (R2 = 0.9875). The studies of thermodynamic behaviour revealed negative values for ∆Go (-26.7036 to -28.1252 kJ/mol), and negative values for ∆Ho (-15.5796 kJ/mol) and ∆So (0.03554 kJ/mol/k) respectively. These indicated the adsorption process was exothermic, feasible and spontaneous in the removal of the Pb (II) ion. The findings demonstrated that the adsorbent could be exploited in the removal of Pb (II) ion from an aqueous solution.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.