Abstract-The oxidized CV3 chondrites can be divided into two major subgroups or lithologies, Bali-like (cV3,,~) and d), in which chondrules, calcium-aluminum-rich inclusions (CAIs) and matrices show characteristic alteration features Krot et al., 1997d;Kimura and Ikeda, 1997). The cv30,B lithology is present in Bali, Kaba, parts of the Mokoia breccia and, possibly, in Grosnaja and Allan Hills (ALH) 85006. It is characterized by the presence of the secondary low-Ca phyllosilicates (saponite and sodium phlogopite), magnetite, Ni-rich sulfides, fayalite (Fa>go), Ca-Fe-rich pyroxenes (Fs 10-5oW045-50) and andradite. Phyllosilicates replace primary Ca-rich minerals in chondrules and CAIs, which suggests mobilization of Ca during aqueous alteration. Magnetite nodules are replaced to various degrees by fayalite, Ca-Fe-rich pyroxenes and minor andradite. Fayalite veins crosscut fine-grained rims around chondrules and extend into the matrix. Thermodynamic analysis of the observed reactions indicates that they could have occurred at relatively low temperatures (<300 "C) in the presence of aqueous solutions. Oxygen isotopic compositions of the coexisting magnetite and fayalite plot close to the terrestrial fractionation line with large A1*Ofayal,te-magnetlte fractionation (-20%0). We infer that phyllosilicates, magnetite, fayalite, Ca-Fe-rich pyroxenes and andradite formed at relatively low temperatures (<300 "C) by fluid-rock interaction in an asteroidal environment.Secondary fayalite and phyllosilicates are virtually absent in chondrules and CAIs in the CV3,d lithology, which is present in Allende and its dark inclusions, Axtell, ALHA81258, ALH 84028, Lewis Cliff (LEW) 86006, and parts of the Mokoia and Vigarano breccias. Instead secondary nepheline, sodalite, and fayalitic olivine are common. Fayalitic olivine in chondrules replaces low-Ca pyroxenes and rims and veins forsterite grains; it also forms coarse lath-shaped grains in matrix. Secondary Ca-Fe-rich pyroxenes are abundant. We infer that the CV3,d lithology experienced alteration at higher temperatures than the cv3,.& lithology. The presence of the reduced and CV3,d lithologies in the Vigarano breccia and W 3 , d and cV3,,~ lithologies in the Mokoia breccia indicates that all CV3 chondrites came from one heterogeneously altered asteroid. The metamorphosed clasts in Mokoia (Krot and Hutcheon, 1997) may be rare samples of the hotter interior of the CV asteroid. We conclude that the alteration features observed in the oxidized CV3 chondrites resulted from the fluid-rock interaction in an asteroid during progressive metamorphism of a heterogeneous mixture of ices and anhydrous materials mineralogically similar to the reduced CV3 chondrites.

The radii and orbital periods of 4000+ confirmed/candidate exoplanets have been precisely measured by the Kepler mission. The radii show a bimodal distribution, with two peaks corresponding to smaller planets (likely rocky) and larger intermediate-size planets, respectively. While only the masses of the planets orbiting the brightest stars can be determined by ground-based spectroscopic observations, these observations allow calculation of their average densities placing constraints on the bulk compositions and internal structures. Yet an important question about the composition of planets ranging from 2 to 4 Earth radii (RÅ) still remains. They may either have a rocky core enveloped in a H2-He gaseous envelope (gas dwarfs) or contain a significant amount of multi-component, H2O-dominated ices/fluids (water worlds). Planets in the mass range of 10-15 MÅ, if half-ice and half-rock by mass, have radii of 2.5 RÅ, which exactly match the second peak of the exoplanet radius bimodal distribution. Any planet in the 2-4 RÅ range requires a gas envelope of at most a few mass%, regardless of the core composition. To resolve the ambiguity of internal compositions, we use a growth model and conduct Monte Carlo simulations to demonstrate that many intermediate-size planets are "water worlds". Keywords: exoplanets / bimodal distribution / ices / water worlds / planet formation Significance Statement: The discovery of numerous exoplanet systems containing diverse populations of planets orbiting very close to their host stars challenges the planet formation theories based on the Solar system. Here we focus on the planets with radii of 2-4 RÅ, whose compositions are debated. They are thought to be either gas dwarfs consisting of rocky cores embedded in H2-rich gas envelopes or water worlds containing significant amounts of H2Odominated fluid/ice in addition to rock and gas. We argue that these planets are water worlds.

The giant impact hypothesis remains the leading theory for lunar origin. However, current models struggle to explain the Moon's composition and isotopic similarity with Earth. Here we present a new lunar origin model. High‐energy, high‐angular‐momentum giant impacts can create a post‐impact structure that exceeds the corotation limit, which defines the hottest thermal state and angular momentum possible for a corotating body. In a typical super‐corotation‐limit body, traditional definitions of mantle, atmosphere, and disk are not appropriate, and the body forms a new type of planetary structure, named a synestia. Using simulations of cooling synestias combined with dynamic, thermodynamic, and geochemical calculations, we show that satellite formation from a synestia can produce the main features of our Moon. We find that cooling drives mixing of the structure, and condensation generates moonlets that orbit within the synestia, surrounded by tens of bars of bulk silicate Earth vapor. The moonlets and growing moon are heated by the vapor until the first major element (Si) begins to vaporize and buffer the temperature. Moonlets equilibrate with bulk silicate Earth vapor at the temperature of silicate vaporization and the pressure of the structure, establishing the lunar isotopic composition and pattern of moderately volatile elements. Eventually, the cooling synestia recedes within the lunar orbit, terminating the main stage of lunar accretion. Our model shifts the paradigm for lunar origin from specifying a certain impact scenario to achieving a Moon‐forming synestia. Giant impacts that produce potential Moon‐forming synestias were common at the end of terrestrial planet formation.