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Critical for the management of artificial recharge operations is detailed knowledge of ground water dynamics near spreading areas. Geochemical tracer techniques including stable isotopes of water, tritium/helium–3 (T/3He) dating, and deliberate gas tracer experiments are ideally suited for these investigations. These tracers were used to evaluate flow near an artificial recharge site in northern Orange County, California, where ∼2.5 × 108 m3 (200,000 acre‐feet) of water are recharged annually. T/3He ages show that most of the relatively shallow ground water within 3 km of the recharge facilities have apparent ages < 2 years; further downgradient apparent ages increase, reaching > 20 years at ∼6 km. Gas tracer experiments using sulfur hexafluoride and xenon isotopes were conducted from the Santa Ana River and two spreading basins. These tracers were followed in the ground water for more than two years, allowing subsurface flow patterns and flow times to be quantified. Results demonstrate that mean horizontal ground water velocities range from < 1 to > 4 km/year. The leading edges of the tracer patch moved at velocities about twice as fast as the center of mass. Leading edge velocities are important when considering the potential transport of microbes and other “time sensitive” contaminants and cannot be determined easily with other methods. T/3He apparent ages and tracer travel times agreed within the analytical uncertainty at 16 of 19 narrow screened monitoring wells. By combining these techniques, ground water flow was imaged with time scales on the order of weeks to decades.

The chemical and isotope (11B/10B, 87Sr/86Sr, 18O/16O, 2H/H, 13C/12C, 14C, and 3He/3H) compositions of groundwater from the upper aquifer system of the Salinas Valley in coastal central California were investigated in order to delineate the origin and processes of groundwater contamination in this complex system. The Salinas Valley has a relatively deep, confined “400‐foot” aquifer, overlain by a “180‐foot” aquifer and a shallower perched aquifer, all made up of alluvial sand, gravel and clay deposits. Groundwater from the aquifers have different 14C ages: fossil (14C = 21.3 percent modern carbon (pmc) for the 400‐foot aquifer and modern (14C = 72.2–98.2 pmc) for the 180‐foot aquifer. Fresh groundwater in all aquifers is recharged naturally and artificially through the Salinas River. The two modes of recharge can be distinguished chemically. We identified several different saline components with distinguishable chemical and isotopic fingerprints. (1) Saltwater intrusion in the northern basin has C1 concentrations up to 1700 mg/L, a Na/Cl ratio less than seawater, a marine Br/Cl ratio, a Ca/Cl ratio greater than seawater, δ11B between +17 and +38‰ and 87Sr/86Sr between 0.7088 and 0.7096. Excess dissolved Ca, relative to the expected concentration for simple dilution of seawater, correlates with 87Sr/86Sr ratios, suggesting base exchange reaction with clay materials. (2) Agriculture return flow is high in NO3 and SO4, with a 87Sr/86Sr = 0.7082,δ11B =19‰and δ13C between −23 and −17‰. The 3H–3He ages (5–17 years) and 14C data suggest vertical infiltration rates of irrigation water of 3–10 m/yr. (3) Nonmarine saline water in the southern part of the valley has high total dissolved solids up to 3800 mg/L, high SO4, Na/Cl ratio >1, δ11B between +24 and +30‰, and 87Sr/86Sr = 0.70852. This groundwater may have acquired its geochemical signature from leaching of sedimentary rocks associated with the Coast Range marine deposits of Mesozoic to early Cenozoic age. The combination of different geochemical and isotopic fingerprints enables us to delineate the impact of salt sources in different areas of the valley and to reconstruct the origin of the SO4‐enriched NO3‐depleted saline plume that is located west of the city of Salinas. We suggest that the latter is derived from a mixture of different natural saline waters rather than from anthropogenic contamination.

The nature and chlorine reactivity of organic constituents in reclaimed water (tertiary-treated municipal wastewater) before, during, and after recharge into groundwater at the Montebello Forebay in Los Angeles County, CA, was the focus of this study. Dissolved organic matter (DOM) in reclaimed water from this site is primarily a mixture of aromatic sulfonates from anionic surfactant degradation, N-acetyl amino sugars and proteins from bacterial activity, and natural fulvic acid, whereas DOM from native groundwaters in the aquifer to which reclaimed water was recharged consists of natural fulvic acids. The hydrophilic neutral N-acetyl amino sugars that constitute 40% of the DOM in reclaimed water are removed during the first 3 m of vertical infiltration in the recharge basin. Groundwater age dating with 3H and 3He isotopes, and determinations of organic and inorganic C isotopes, enabled clear differentiation of recent recharged water from older native groundwater. Phenol structures in natural fulvic acids in DOM isolated from groundwater produced significant trihalomethanes (THM) and total organic halogen (TOX) yields upon chlorination, and these structures also were responsible for the enhanced SUVA and specific fluorescence characteristics relative to DOM in reclaimed water. Aromatic sulfonates and fulvic acids in reclaimed water DOM produced minimal THM and TOX yields.

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