Context. Most disks observed at high angular resolution show signs of substructures, such as rings, gaps, arcs, and cavities, in both the gas and the dust. To understand the physical mechanisms responsible for these structures, knowledge about the gas surface density is essential. This, in turn, requires information on the gas temperature. Aims. The aim of this work is to constrain the gas temperature as well as the gas surface densities inside and outside the millimeter-dust cavities of two transition disks: LkCa15 and HD 169142, which have dust cavities of 68 AU and 25 AU, respectively. Methods. We use some of the few existing ALMA observations of the J = 6-5 transition of 13CO together with archival J = 2−1 data of 12CO, 13CO, and C18O. The ratio of the 13CO J = 6−5 to the J = 2−1 transition is used to constrain the temperature and is compared with that found from peak brightness temperatures of optically thick lines. The spectra are used to resolve the innermost disk regions to a spatial resolution better than that of the beam of the observations. Furthermore, we use the thermochemical code DALI to model the temperature and density structure of a typical transition disk as well as the emitting regions of the CO isotopologs. Results. The 13CO J = 6−5 and J = 2−1 transitions peak inside the dust cavity in both disks, indicating that gas is present in the dust cavities. The kinematically derived radial profiles show that the gas is detected down to 10 and 5-10 AU, much farther in than the dust cavities in the LkCa15 and HD 169142 disks, respectively. For LkCa15, the steep increase toward the star in the 13CO J = 6−5 transition, in contrast to the J = 2−1 line, shows that the gas is too warm to be traced by the J = 2−1 line and that molecular excitation is important for analyzing the line emission. Quantitatively, the 6−5/2−1 line ratio constrains the gas temperature in the emitting layers inside the dust cavity to be up to 65 K, warmer than in the outer disk, which is at 20-30 K. For HD 169142, the lines are optically thick, complicating a line ratio analysis. In this case, the peak brightness temperature constrains the gas in the dust cavity of HD 169142 to be 170 K, whereas that in the outer disk is only 100 K. The data indicate a vertical structure in which the 13CO 6-5 line emits from a higher layer than the 2-1 line in both disks, consistent with exploratory thermochemical DALI models. Such models also show that a more luminous central star, a lower abundance of polycyclic aromatic hydrocarbons, and the absence of a dusty inner disk increase the temperature of the emitting layers and hence the line ratio in the gas cavity. The gas column density in the LkCa15 dust cavity drops by a factor of >2 compared to the outer disk, with an additional drop of an order of magnitude inside the gas cavity at 10 AU. In the case of HD 169142, the gas column density drops by a factor of 200–500 inside the gas cavity. Conclusions. The gas temperatures inside the dust cavities steeply increase toward the star and reach temperatures of up to 65 K (LkCa15) and 170 K (HD 169142) on scales of ~15–30 AU, whereas the temperature gradients of the emitting layers in the outer disks are shallow, with typical temperatures of 20-30 and 100 K, respectively. The deep drop in gas column density inside the HD 169142 gas cavity at <10 AU could be due to a massive companion of several MJ, whereas the broad dust-depleted gas region from 10 to 68 AU for LkCa15 may imply several lower mass planets. This work demonstrates that knowledge of the gas temperature is important for determining the gas surface density and thus whether planets, and if so what kinds of planets, are most likely to be carving the dust cavities.

Gas-phase sulphur-bearing volatiles appear to be severely depleted in protoplanetary disks. The detection of CS and the non-detections of SO and SO2 in many disks have shown that the gas in the warm molecular layer, where giant planets accrete their atmospheres, has a high C/O ratio. In this Letter, we report the detection of SO and SO2 in the Oph-IRS 48 disk using ALMA. This is the first case of prominent SO2 emission detected from a protoplanetary disk. The molecular emissions of both molecules is spatially correlated with the asymmetric dust trap. We propose that this is due to the sublimation of ices at the edge of the dust cavity and that the bulk of the ice reservoir is coincident with the millimetre-sized dust grains. Depending on the partition of elemental sulphur between refractory and volatile materials, the observed molecules can account for 15–100% of the total volatile sulphur budget in the disk. In stark contrast to previous results, we constrain the C/O ratio from the CS/SO ratio to be < 1 and potentially solar. This has important implications for the elemental composition of planets forming within the cavities of warm transition disks.

Context. The formation of planets is expected to be enhanced around snowlines in protoplanetary disks, in particular around the water snowline. Moreover, freeze-out of abundant volatile species in disks alters the chemical composition of the planet-forming material. However, the close proximity of the water snowline to the host star combined with the difficulty of observing water from Earth makes a direct detection of the water snowline in protoplanetary disks challenging. HCO+ is a promising alternative tracer of the water snowline. The destruction of HCO+ is dominated by gas-phase water, leading to an enhancement in the HCO+ abundance once water is frozen out. Aims. Following earlier observed correlations between water and H13CO+ emission in a protostellar envelope, the aim of this research is to investigate the validity of HCO+ and the optically thin isotopologue H13CO+ as tracers of the water snowline in protoplanetary disks and the required sensitivity and resolution to observationally confirm this. Methods. A typical Herbig Ae disk structure is assumed, and its temperature structure is modelled with the thermochemical code DALI. Two small chemical networks are then used and compared to predict the HCO+ abundance in the disk: one without water and one including water. Subsequently, the corresponding emission profiles are modelled for the J = 2−1 transition of H13CO+ and HCO+, which provides the best balance between brightness and the optical depth effects of the continuum emission and is less affected by blending with complex molecules. Models are then compared with archival ALMA data. Results. The HCO+ abundance jumps by two orders of magnitude over a radial range of 2 AU outside the water snowline, which in our model is located at 4.5 AU. We find that the emission of H13CO+ and HCO+ is ring-shaped due to three effects: destruction of HCO+ by gas-phase water, continuum optical depth, and molecular excitation effects. Comparing the radial emission profiles for J = 2−1 convolved with a 0′′.05 beam reveals that the presence of gas-phase water causes an additional drop of only ~13 and 24% in the centre of the disk for H13CO+ and HCO+, respectively. For the much more luminous outbursting source V883 Ori, our models predict that the effects of dust and molecular excitation do not limit HCO+ as a snowline tracer if the snowline is located at radii larger than ~40 AU. Our analysis of recent archival ALMA band 6 observations of the J = 3−2 transition of HCO+ is consistent with the water snowline being located around 100 AU, further out than was previously estimated from an intensity break in the continuum emission. Conclusions. The HCO+ abundance drops steeply around the water snowline, when water desorbs in the inner disk, but continuum optical depth and molecular excitation effects conceal the drop in HCO+ emission due to the water snowline. Therefore, locating the water snowline with HCO+ observations in disks around Herbig Ae stars is very difficult, but it is possible for disks around outbursting stars such as V883 Ori, where the snowline has moved outwards.

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The complex organic molecules (COMs) detected in star-forming regions are the precursors of the prebiotic molecules that can lead to the emergence of life. By studying COMs in more evolved protoplanetary disks we can gain a better understanding of how they are incorporated into planets. This paper presents ALMA band 7 observations of the dust and ice trap in the protoplanetary disk around Oph IRS 48. We report the first detection of dimethyl ether (CH3OCH3) in a planet-forming disk and a tentative detection of methyl formate (CH3OCHO). We determined column densities for the detected molecules and upper limits on non-detected species using the CASSIS spectral analysis tool. The inferred column densities of CH3OCH3 and CH3OCHO with respect to methanol (CH3OH) are of order unity, indicating unusually high abundances of these species compared to other environments. Alternatively, the 12CH3OH emission is optically thick and beam diluted, implying a higher CH3OH column density and a smaller emitting area than originally thought. The presence of these complex molecules can be explained by thermal ice sublimation, where the dust cavity edge is heated by irradiation and the full volatile ice content is observable in the gas phase. This work confirms the presence of oxygen-bearing molecules more complex than CH3OH in protoplanetary disks for the first time. It also shows that it is indeed possible to trace the full interstellar journey of COMs across the different evolutionary stages of star, disk, and planet formation.