We present a method for determining the diffusion lengths of Ga adatoms on GaN by combining profiling of the tops of GaN stripes obtained by selective area MOCVD and a diffusion growth model. We deduce very high values of the diffusion lengths on tops of <11–20>‐oriented stripes at 1040 °C which range from 6 μm under nitrogen‐rich to 24 μm under hydrogen‐rich atmosphere in the reactor. The obtained results show in particular that Ga‐catalyzed growth of GaN nanostructures and nanowires should not be limited by Ga influx and thus the exceptional growth rate is anticipated in such cases.

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We present a new approach for synthesis of GaN nanowires and microwires by metal organic chemical vapor deposition via a thin titanium film evaporated onto sapphire substrate prior to growth. Titanium etches a two-dimensional GaN layer deposited at the initial stage and GaN nanowires subsequently emerge at the boundaries of the etched grains. These wires grow at an exceptional elongation rate of 18 μm/min and extend radially at a rate of 0.14 μm/min. The GaN layer between the wires grows at a rate of 0.1 μm/min. High material quality of these structures is confirmed by micro-photoluminescence spectroscopy. We investigate the initial nucleation stage, the time evolution of the wire length and diameter, the length and diameter distributions and speculate about a mechanism that yields the observed growth behavior.

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