In recent years, financial losses due to salinity changes threat bivalve industry. In natural habitat, marine bivalves should be adapted to a series of environmental stressors, including biotic (virus, bacteria and protozoan) and abiotic (salinity, temperature and heavy metal) factors. It is known that salinity fluctuations able to change distribution and vital parameters of bivalves. Suboptimal salinity conditions resulted in changes in defense mechanism, growth, free amino acid, heart rate, oxygen consumption and filtration rate. However, it is necessary to determine the optimal salinity level of cultured bivalves to avoid the risk of mortality and improve growth rate. Therefore, this study aimed to review the findings from various reports in vitro and in vivo conditions which evaluated physiological and immunological responses of different bivalve species submitted to different salinity concentrations. The information of present study is very important in understanding the physiological responses of bivalves, which are living in highly changeable environment such as estuarine.
Purpose – The purpose of this paper is to examine the relationship between knowledge management (KM) processes and supply chain performance, with information technology/information system (IT/IS) support, supply chain integration, and supply chain strategy as moderators. Design/methodology/approach – Drawing on the knowledge-based view, a theoretical framework is developed consisting of six KM processes: knowledge creation, knowledge capture, knowledge organization, knowledge storage, knowledge dissemination, and knowledge application, and the performance of supply chain is evaluated in terms of four Supply Chain Operations Reference (SCOR) process elements: Plan, Source, Make, and Delivery. Structural equation modeling is employed using a sample of 78 Iranian manufacturers in mechanical and engineering industry. Findings – Empirical results show that KM processes have a significant impact on supply chain performance which is positively moderated by IT/IS support and supply chain integration. While the moderating effect of IT/IS support is found to be considerably stronger, the relationship between KM processes and supply chain performance is not significantly different in lean and agile supply chains. Research limitations/implications – Since the sample for this study is small and drawn only from manufacturing companies in mechanical and engineering industry, it would be important to conduct further empirical studies with larger samples from a wider range of industries to improve and strengthen our analyses and provide more conclusive and generalizable results. Originality/value – Through empirical study, a better understanding of the impact of KM processes on supply chain performance and the moderating role of IT/IS support and supply chain integration can be gained.
In this research, the reinforcing effect of fillers including canola stalk, paulownia and nanoclay, in polypropylene (PP) has been investigated. In the sample preparation, 50 wt% of lignocellulosic materials and 0, 3, and 5 wt% of nanoclay particles were used. The results showed that while flexural and tensile properties were moderately enhanced by the addition of nanoclay in the matrix, notched Izod impact strengths decreased dramatically. However, with increase in the nanoclay content (5 wt%), the flexural and tensile properties decreased considerably. The mechanical properties of composites filled with paulownia are generally greater than canola stalk composites, due to the higher aspect ratio. The thickness swelling and water absorption of the composites significantly decreased with the increase in nanoclay loading. Except tensile modulus, the differences between the type of fibrous materials and nanoclay contents had significant influence on physicomechanical properties. Morphologies of the composites were analyzed using transmission electron microscopy (TEM) and X‐ray diffraction (XRD), and the results showed increased d‐spacing of clay layers indicating enhanced compatibility among PP, clay, and lignocellulosic material. TEM micrographs also confirmed that the composites containing 3 wt% nanoclay had uniform dispersion and distribution of clay layers in the polymer matrix. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013
The stereoselectivity of aldol reactions of chiral reactants can be factorized into to three stereocontrol elements: the diastereoface selectivities of the ketone enol(ate) and aldehyde and the relative topicity of the coupling. Application of the multiplicativity rule to these elements leads to the prediction that kinetic resolution (KR) should be possible if all three stereocontrol elements are strongly biased. As a corollary, the enantioselectivity of the kinetic resolution should be switchable by a change in the sense of selectivity of any of the stereocontrol elements. This hypothesis was tested using aldehyde and ketone reactants with high diastereoface selectivities and developing reaction conditions that strongly favor either syn or anti relative topicity. The aldehyde 2 undergoes aldol reactions with near-exclusive Felkin diastereoface selectivity, and hydroxy-protected derivatives of ketone 1 (R = MOM, Et(3)Si, or Ac) undergo aldol reactions with high diastereoface selectivity to give 3,5-trans adducts. High levels of anti and syn relative topicity were obtained with dicyclohexylboron enolates and Ti(O(i)Pr)(4)Li "ate" enolates, respectively. Using these enolates, aldol reactions of (+/-)-2 with (+/-)-1 gave two of the eight possible diastereomeric adducts (3 from a diastereoselective like combination of reactant enantiomers and 4 from a diastereoselective unlike combination) predominantly (>95% of the adducts) in ratios of 0.05-20:1; boron enolates favored the like reaction (3:4, 15-20:1) and Ti "ate" enolates favored the unlike reaction (3:4, 1:10-20). Under these conditions, the ratio of like and unlike products is a measure of the mutual kinetic enantioselection (MKE) and reflects the ratio of the rate constants for the competing like and unlike reactions. For each of the four diastereomers of 1, the reactions with the highest MKEs in favor of the like (3) or unlike products (4) were repeated using highly enantioenriched ketone. These reactions occurred with the expected KR (s = 10-20) allowing selective access to enantioenriched diastereomers of 3 or 4 from (+/-)-2. These adducts are useful for polypropionate synthesis, and this design strategy for KR should be applicable to related processes.
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