No abstract

The Hamisana shear zone (HSZ) is a broad zone of deformation, approximately 50 km wide and at least 300 km long, making it one of the largest basement structures in NE Africa. It has been interpreted as a Precambrian suture, as a zone of strike-slip displacement, or as a zone of crustal shortening. The results of new Rb-Sr and U-Pb zircon geochronological studies indicate that the northern HSZ was thermally active during the Pan-African event until c. 550 Mg ago; initiation of the structure may have begun 40-110 Ma earlier. All units have low initial ''Sr/*% ratios, indicating juvenile derivation. The timing of activity in the HSZ is 50-150 Ma younger than collisional suturing and terrane assembly in the Arabian-Nubian Shield but is similar to the 655-540Ma Najd fault system of Egypt and Arabia. Deformation and metamorphism along the HSZ clearly post-date terrane accretion and probably are closely related to the Najd tectonic cycle. The most important deformation of the HSZ is unrelated to suturing, and at least one late Precambrian suture must extend west from Arabia into the interior of N. Africa.

The demand for natural fungicides to replace synthetic ones has surged since toxic residues persist in soils, causing environmental contamination and posing a serious threat to worldwide public health. In the context of crop protection and enhancing the efficiency and safety of fungicides, nanotechnology is an eco-friendly strategy in managing fungal pathogens. In the present study, essential oils were isolated from the peels of four citrus fruits (Citrus lemon, Citrus aurantifolia, Citrus maxima, and Citrus sinensis) and were investigated using gas chromatography-mass spectrometric analysis. Monoterpene hydrocarbon was the most predominant group and limonene was the most abundant in the four oils. The antifungal potential of the oils was investigated, and the most active oil (Citrus lemon) was loaded into hexosomal dispersion, and its antifungal potential was retested against the same fungi. The structurally unique nano-based formulation showed great potency for fungal control. To the best of our knowledge, it is the first time the oil of Citrus lemon in nano-hexosomes has been formulated and its fungicidal activity examined. The data collected suggest that citrus essential oils (CEOs), especially when nano-formulated, could be successfully used in integrated fungus management programs.

Interest in plant-based diets has been on the rise in recent years owing to the potential health benefits of their individual components and the notion that plant-based diets might reduce the incidence of several diseases. Egyptian dukkah and Syrian za’atar are two of the most historic and famous Middle Eastern herbal blends used for their anti-inflammatory, hypolipidemic, and antidiabetic effects. Headspace SPME-GCMS and HPLC-DAD were adopted for characterizing the aroma profile and phenolic compounds of both herbal blends, respectively. Further, vapor-phase minimum inhibitory concentration was employed for assessing each blend’s antibacterial potential, while their antioxidant potential was estimated via in vitro antioxidant assays. SPME headspace analysis indicated the abundance of ethers and monoterpene hydrocarbons, while HPLC revealed the presence of several phenolics including rosmarinic acid, ferulic acid, and rutin. Biological investigations affirmed that vapor-phase of the tested blends exhibited antibacterial activities against Gram-positive and Gram-negative pathogens, while the antioxidant potential of the blends was investigated and expressed as Trolox (125.15 ± 5.92 to 337.26 ± 13.84 μM T eq/mg) and EDTA (18.08 ± 1.62 to 51.69 41 ± 5.33 μM EDTA eq/mg) equivalent. The presented study offers the first insight into the chemical profile and biological activities of both dukkah and za’atar.