In this paper, at first, we focus on a FRW universe in which the dark energy candidate satisfies the Polytropic equation of state and study thermodynamics of dark energy. Bearing the thermal fluctuation theorem in mind, we establish a relation between the thermal fluctuation of system and mutual interaction between the dark energy and dark matter. Generalization to a viscous Polytropic gas is also investigated. We point to a condition for decaying dark energy candidate into the dark matter needed for alleviating coincidence problem. The effects of dark energy candidates and their interactions with other parts of cosmos on the horizon entropy as well as the second law of thermodynamics are also addressed. Our study signals us to a correction term besides the Bekenstein entropy which carries the information of the dark energy candidate, its interaction with other parts of cosmos and its viscosity.

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