18 gem-dimethyl stabilized hydrodipyrrins with diverse α-substituents have been prepared and examined in directed syntheses of unsymmetrically substituted hydroporphyrins.

The two pyrroline units of bacteriochlorins can now bear gem-dialkyl or diaryl groups (L), which project above and below the macrocycle plane, whereas dimethyl groups generally have been accessible previously.

One-pot synthesis of 1,2,3-triazole tethered benzimidazo[1,2-a]quinolines through a multi-component reaction is demonstrated. Overall one C–C bond and three C–N bonds are formed in a single step.