B i -S r -C a -C u -0 (BSCCO) superconducting whiskers (2212 phase) were prepared by heating in air the compacted specimens of the mixtures of melt-quenched Bi2Srj,Ca2Cu4AliOx powders and alumina powders. Formation of the whiskers depends on the composition and the applied pressure of the compacts. The optimum composition of the melt-quenched products for preparing the long whiskers is Bi2Sr2Ca2Cu4Ali0x. Superconducting whiskers < 1 mm in length (2212 phase) containing an excess amount of copper were grown numerously from the specimen compacted at 20 MPa; long whiskers (2212 phase) of 1-5 mm in length were obtained from that compacted at 180 MPa. These whiskers showed diamagnetic signals below Tc -80 K.
Trends in negative pressure over a few thousand cavitation events have been investigated for a Berthelot system comprising water/stainless steel/tube/sealing Ni plug in order to study the effects and extents of surface pre-treatments for the sealing metal, polishing, etching, and electroplating. The polishing and etching pre-treatments separated two kinds of cavitation nuclei on the metal surface; gases trapped within pores (crevices) (i) in the metal surface, and (ii) extending deep into the metal bulk. The latter, although much tougher, influenced negative pressure for a thousand cavitation events at most. The rise in negative pressure after a total of 1800 temperature cycles levelled off at around -115 bar (-11.5 MPa) irrespective of the surface finishes of the plugs. Electroplated plugs gave poor increasing trends owing to the co-deposited hydrogen. Impurity gases in the metal did limit the rise in negative pressure. These results, together with those reported before, have validated the authors extended gas-trapping crevice model, negative pressure is eventually limited by a supply of gas from sources in the metal bulk to surface crevices.
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