Mixtures of elementary oxides, MgO–Al2O3, were used to fabricate transparent polycrystalline magnesium aluminate spinel specimens by means of the spark plasma sintering technique. A sintering aid, 1 wt% of LiF, was added to the mixed powder. The presence of the additive promotes the synthesis of spinel that starts at 900°C and is completed at 1100°C. The LiF additive wets spinel on its melting and promotes densification, which is completed at 1600°C. LiF vapor plays a cardinal role in eliminating residual carbon contamination and in the fully dense state, allows attaining a 78% level of optical transmittance. The optimal conditions for achieving adequate transparency were determined and the role of the LiF addition in the various stages of the process is discussed.
The thermodynamic properties of liquid bismuth have been explored from the melting point to 1100 °C by high-resolution measurements of the density, the heat capacity and the static structure factor. These physical properties display a number of anomalies. In particular, we have observed evidence for the presence of a temperature-driven liquid-liquid structural transformation that takes place at ambient pressure. The latter is characterized by a density discontinuity that occurs at 740 °C. Differential thermal analysis measurements revealed the endothermal nature of this transformation. A rearrangement of liquid bismuth structure was found by neutron diffraction measurements, supporting the existence of a liquid-liquid transformation far above the liquidus.
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