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In this work, the structural and optical properties of the 60SiO 2 e20ZnOe20TiO 2 system (in mol%) doped with 1 mol% of Eu 3þ were evaluated. Stable and transparent sols, homogeneous gels, and powders were prepared by a soft chemical process followed by annealing from 700 to 1100 C. Visible emission was observed in the photoluminescence (PL) spectra from 570 to 700 nm owing to the Eu 3þ ions, with the most intense emission peaks at 614 and 590 nm related to the 5 D 0 / 7 F 2 and 5 D 0 / 7 F 1 transitions, corresponding to red (R) and orange (O) colors, respectively. The R/O intensity ratios between 3.16 and 3.73 were observed and correlated to the structural properties of the host. X-ray diffraction patterns indicated that the reduction of PL at 614 nm and changes in the R/O values were due to the crystallization process. In addition, the FTIR spectra showed a gradual decrease of the hydroxyl absorption bands around 3436 and 1640 cm À1 and an increase of the bands related to TieOeTi and SieOeSi linkages, indicating polymerization and densification process of the host was achieved above 700 C. Moreover, increasing the annealing temperature resulted in the formation of ZnTiO 3 and Zn 2 TiO 4 crystalline phases, as well as rutile TiO 2. Finally, intensity parameters (U l), and quantum efficiency were calculated by applying JuddeOfelt theory to Eu 3þ ions, which showed that the Eu 3þ-doped samples can be used in displays and LEDs.