PNIPAM hydrogels functionalized with gold nanoparticles were prepared by making use of catechol redox chemistry. For this purpose catechol groups were introduced in the PNIPAM network during the cross-linking polymerization process (PNIPAM–catecholx hydrogel). These groups act as reducing agents of HAuCl4, which enables the functionalization of the PNIPAM with gold nanoparticles (PNIPAM–catecholx@Au hydrogel). The rheological study shows that catechol groups reinforce the hydrogel structure. A stronger effect was observed after the functionalization of the hydrogel with gold nanoparticles. This influence could be easily observed since the variation of G′ with the MBA mole fraction was fitted to a power-law expression G′ ∼ x MBA a , with a = 1.6 for PNIPAMx hydrogels, a = 2.3 for PNIMPAM–catecholx hydrogels and a = 3.2 for PNIMPAM–catecholx@Au hydrogels. The capability of the PNIPAM–catecholx@Au hydrogel to act as a tunable catalyst was demonstrated with a model reduction reaction. The half-lifetime at 25 °C was 10.5 min; however, at 38 °C the half-lifetime was 133 min.

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A new family of amine- and ammonium-terminated hyperbranched polycarbosilanes (PCS) and dendrimers has been synthesized. The functionalization of a polycarbosilane matrix was carried out with peripheral allyl groups by two strategies in the case of PCS: 1) hydrosilylation of allyl amines with PCS containing terminal Si-H bonds, or 2) hydrosilylation of PCS-allyl with an aminosilane. Dendrimers with terminal amine groups were synthesized by hydrosilylation of allydimethylamine. Quaternized systems with MeI are soluble and stable in water or other protic solvent. The antibacterial properties of the ammonium-terminated hyperbranched polycarbosilanes and dendrimers have been evaluated showing that they act as potent biocides against Gram-positive and Gram-negative bacterial strains.