Struktur-Eigenschafts-Beziehungen kristallin-fldssiger Seitenkettenpolymere werden untersucht. Die Anderung der mcsomorphen Eigenscliaften bei gezielten Strukturvariationen werden dabei mit den entsprechcnden Resultaten an den Monomercn verglichen. Variicrt werden starrer mesogener Grundkorper, Spacer und Flugelgruppe.
Tep.nzompon-Mudtco-tcpucmannuuecme noauaepbi. B n u n u e omaenbnb6x cmpytcmypicbrx ane~enmoe Ha acuaicoxpucmannuuecicue csoiicmsa n o m x u o m a n o s c a e 3 0 z e i t~b~~u 60li-osbk~u zpynnawuBCCJIeAOBaHa CBH3b MelK,Q' CTPYKTYPOP II CBOPCTBBMIZ lKllAKO-KpMCTaJIJIBqeCKIIX nOJIMMepOB C 6OKOBbIMM rpynnaMM. CPaBHABBIOTCR I13MeHeHHR Me30MOPl#IHbIX CBOPCTB B 3aBBCHMOCTH OT BapHaqllll CTPYKTYPbI C COOTBeTCTByIO~IZMH pe3yJIbTaTaMM AJIH MOHOMepOB. Id3MeHRIOTCR XeCTKlle Me30lXHHbIe 4parMeHTb1, Cn3CephI M r n 6~~e 60KOBbIe I'pJ'nIIbI.Therntotrop liquid crystalline polymers. The effect of the structure units on the liquid crystalline properties of polysiloxanes with mesogenic side groups T h e structure-property relationships of liquid crystalline comb-like polymers are discussed. The changes of mesomorphic properties a t specific structure variations are correlated with results from the monomers. The rigid mesogenic core, the spacer and the wing group are variated.
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