Relatively small changes in glass composition might have drastic consequences on the evaporation
rates of volatile glass components in glass melting furnaces. Transpiration evaporation tests have
been applied to measure the impact of minor glass composition changes on the evaporation rates of
volatile glass components in simulated furnace atmospheres. The results of these laboratory
evaporation tests were used to develop and optimize an universally applicable evaporation model to
estimate evaporation rates and dust emissions for industrial glass melt furnaces. Mass transfer
relations for the transport of volatile glass melt species into the turbulent gas phase were used to
upscale the evaporation models valid for the lab tests to applications for industrial glass furnaces.
In this paper, the impact of sulfur and chlorides on the evaporation rates of sodium and potassium
from multi-component silicate melts for industrial glass production will be demonstrated.
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