This paper aims to analyze the generalization of Lemaître-Tolman-Bondi (LTB) spacetime for dissipative dust under the influence of Palatini f (R) gravity. We explore the modified field equations, kinematical variables and mass function in this scenario. We construct Bianchi identities using conservation and differential equations for shear, expansion and curvature scalar in the background of Palatini f (R) gravity. We calculated the scalar functions coming from the orthogonal decomposition of Riemann tensor in this framework. These scalar functions known as structure scalars have been explored for LTB spacetime using modified field equations. The symmetric properties of LTB spacetime have been discussed using two subcases. We found that generalized LTB spacetime has properties comparable with LTB and obtained structure scalars in both cases which have similar dependence on material profile even in Palatini gravity.

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