Tetrapyrrolic systems largely inspired by nature have attracted much attention in organic electronics and biomedical applications owing to their planar structure and extended [Formula: see text]-conjugated double bonds. As a result, delocalization of [Formula: see text]-electron cloud leads the excellent optical absorption and fluorescent properties. Nonetheless, the utilization of non-covalent interactions result in the self-assembled nanostructures providing applications in bioimaging and electronics. In this review, it is demonstrated that the recent reports on the self-assembly in tetrapyrrolic systems via supramolecular interactions lead to well-defined nanoarchitectures. Moreover, the importance of porphyrin based derivatives in nanoelectronics and chemotherapeutic applications is reported. Therefore, the inclination of tetrapyrroles towards the design and development of novel supramolecular nanostructures are considered the hallmark for nanorobotics, shape memory polymers and bionic arms.

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Donor-Acceptor (D-A) systems based on phenoxazine – phthalocyanine (PXZ-Pc) and phenoxazine – zinc phthalocyanine (PXZ-ZnPc) have been designed and synthesized. Both D-A systems are characterized using various spectroscopic and electrochemical techniques including in-situ methods. Optical absorption studies suggest that both Soret and Q bands of these D-A systems are hypsochromically and bathochromically shifted, when compared to its individual constituents. The study supported by theoretical calculations shows clearly that there exists a negligible electronic communication in the ground state between donor phenoxazine and acceptor phthalocyanine. However, attractively, both D-A systems exhibit noteworthy fluorescence emission quenching (90–99%) of the phthalocyanine emission compared to its reference compounds. The fluorescence emission quenching featured at the excited-state intramolecular photoinduced electron transfer from ground state of phenoxazine to the excited state of phthalocyaine/zinc phthalocyanine. The rates of electron-transfer ([Formula: see text] of these D-A systems are found in the range of 5.7 × 108 to 2.8 × 109 s[Formula: see text] and are according to solvent polarity.

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