The western part of the Kedougou Kenieba Inlier is located in the West African Craton. It consists of paleoproterozoic NE-trending elongate belts (subprovinces) of metavolcanic and granitic rocks that alternate with metasedimentary belts. Major linear fault such as the MTZ which also approximate a north-easterly trend form the eastern boundaries. The field observations and geophysics analyses were completed by a microscopic study. Based on these data we define across this region four lithostructural domains from east to west. The western domain is structurally complex. The rocks of this domain have been subjected to a complex history of polyphase deformation and metamorphism. The structural analyse allow us to distinguished three deformation events. The deformation results in the formation of D1 thrust tectonic and D2 and D3 transcurrent tectonic. The structural evolution of the Mako Belt is characterized by deformation dominated by the intrusion of large TTG batholiths (D1) followed by basins formation and transpression accommodating oblique convergence and collision (D2 and D3). The change from thrusting (D1 deformation to transcurrent motion (D2 and D3) is recorded in the marginal basin of the central domain and in Tinkoto pull apart basin. The timing of these basins indicates a diachronous evolution. Deformation styles within the basin are compatible with a dextral transpression which terminated at ca 2090 Ma. Small extensional basins formed over the rocks of the Mako Belt are filled with continental detrital sedimentary rocks that show weak foliation and active felsic volcanism. We suggest that the sinistral transpressive tectonic associated with oblique subduction may have generated the pull-apart basin and subaqueous volcanism. In part these features are now related to terrain accretion, thrusting and strike slip movement during oblique convergence. The inversion of the large scale structural evolution from thrusting to strike slip is common to modern orogenies.

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The calc-alkaline volcanic formations in the western part of the Kedougou-Kenieba inlier crop out in three complexes: the Foulde in the North and the areas of Mako and Baniomba in the South. These complexes which either combine with the tholeiites or cut across the sedimentary formations are composed of thin veins and massive lava flows. They have many petrographic similarities and show chemical characteristics that resemble those of island-arc rocks. At the tectonic level, the D1 deformation phase preceding the formation of the basins and the transpressive tectonics including an oblique convergence may account for the structural evolution of the Mako volcanic belt. Its occurrence in different basins may be evidenced by the composition of some lithophilic components like the Sr, Ba, U, Rb and the composition of clinopyroxenes enriched in TiO2, FeO, Na 2 O in the Foulde calc-alkaline volcanic rocks that developed in a sedimentary environment.

The volcanic tuffs of Senegal-Oriental in Mako area are produced during a calc-alkaline volcanism which occurs in this region and which is dated from about 2.3-1.95 Ga. Despite their altered appearance, the X-Ray diffractions show mineral paragenesis: Quartz-Kaolinite-Illite and an important amorphous phase. On the Ternary Keil-Rankin diagram for the CaO-SiO 2-Al 2 O 3 the volcanic tuffs of Mako area are situated between pozzolan and the fly ash. The difference between silica and lime is greater than 34% in these volcanic tuffs. In this study, they have been mixed with Portland cement to obtain pozzolanic cements respectively with 20%, 30%, 35% and 40% of addition of volcanic tuffs. The pozzolanic reactivity is highlighted by the compressive strength increase until 90 days of conservation in water. It supposes that the vitreous phase of the volcanic tuffs reacts with the free CaO (CaOf) of Portland cement to produce new hydrated minerals. This study has a positive economic and environmental impact. Because the time of grinding of pozzolanic cements is reduced. Also, the addition of volcanic tuffs reduces the production of clinker, then the CO 2 emission.