Sonoluminescence (SL) radiation from different solutions of phosphoric acid has been studied in the framework of a hydro-chemical simulation. By calculating the phase diagrams of an SL bubble in different concentrations of phosphoric acid, the optimum solution for acquiring maximum SL emission has been specified as the solution of around 30 wt.% acid. It is shown that the SL temperature and the number of particles inside the bubble at the time of SL emission are two important factors determining the optimum solution. Numerical calculation of the SL intensity shows that the optimum solution has an intensity of about 20 times greater than that of water. Also, contributions of different energy sources in creation of thermal energy of the bubble have been calculated. The result indicates that the work of external driving pressure is the most important factor to determine the ultimate thermal energy of the bubble at the time of SL emission. Based on this result, we have reasoned out that in the determination of the optimum solution, the role of viscosity of the acid solutions is more important than the vapor pressure.
Using a hydrochemical simulation, temperature dependency of single-bubble sonoluminescence (SL) in a concentrated solution of sulfuric acid has theoretically been studied. With calculating the phase diagrams of an SL bubble in the solution of 85% acid, maximum acquirable SL emissions at different ambient temperatures were calculated. The results show that the SL emission in sulfuric acid increases with increment in the ambient temperature. This temperature dependency is in opposition to that observed in experiments for SL in water. The difference originates from different instability mechanisms determining the ultimate phase parameters of SL in water and sulfuric acid. In water, due to the smallness of viscosity, the ultimate phase parameters are determined by the shape instability. However, in sulfuric acid the phase parameters are restricted by positional instability due to the largeness of the liquid viscosity.
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